Research output: Contribution to journal › Article › peer-review
Surface active monomers: from micellar solution properties to molecular characteristics. / Lezov, A. A.; Fetin, P. A.; Gubarev, A. S.; Lezova, A. A.; Vezo, O. S.; Senchukova, A. S.; Mikhailova, M. E.; Mikusheva, N. G.; Zorin, I. M.; Tsvetkov, N. V.
In: Journal of Polymer Research, Vol. 27, No. 12, 384, 12.2020.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Surface active monomers: from micellar solution properties to molecular characteristics
AU - Lezov, A. A.
AU - Fetin, P. A.
AU - Gubarev, A. S.
AU - Lezova, A. A.
AU - Vezo, O. S.
AU - Senchukova, A. S.
AU - Mikhailova, M. E.
AU - Mikusheva, N. G.
AU - Zorin, I. M.
AU - Tsvetkov, N. V.
N1 - Funding Information: Lezov, Fetin, Gubarev, Senchukova, Mikusheva and Mikhailova are grateful for the financial support to the Russian Foundation for Basic Research (project № 18–33-20013). The measurements were partially carried out using the instruments of the Analytical Resource Center and Centre for diagnosis of functional materials in medicine, pharmacology and nanoelectronics of Saint‐Petersburg State University. Publisher Copyright: © 2020, The Polymer Society, Taipei. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.
PY - 2020/12
Y1 - 2020/12
N2 - Hydrodynamic methods and light scattering were used in the studies of solutions of a surface active monomer 11-acryloyloxyundecyltrimethylammonium bromide (AUTA-Br) and its polymers in 0.05 M NaCl. Aqueous solutions of AUTA-Br monomer in the concentration range of 4 to 16 CMC contain individual molecules and near-spherical AUTA-Br aggregates. The pAUTA-Br polymers possess rather high equilibrium rigidity (11.8 nm). This high value of equilibrium rigidity found for pAUTA-Br macromolecules is apparently caused by two factors: the presence of a bulky side substituent in each AUTA-Br monomer unit and incomplete suppression of electrostatic interactions between neighboring monomer units in the backbone.
AB - Hydrodynamic methods and light scattering were used in the studies of solutions of a surface active monomer 11-acryloyloxyundecyltrimethylammonium bromide (AUTA-Br) and its polymers in 0.05 M NaCl. Aqueous solutions of AUTA-Br monomer in the concentration range of 4 to 16 CMC contain individual molecules and near-spherical AUTA-Br aggregates. The pAUTA-Br polymers possess rather high equilibrium rigidity (11.8 nm). This high value of equilibrium rigidity found for pAUTA-Br macromolecules is apparently caused by two factors: the presence of a bulky side substituent in each AUTA-Br monomer unit and incomplete suppression of electrostatic interactions between neighboring monomer units in the backbone.
KW - Polyelectrolyte
KW - Self-assembly
KW - Surfactant monomer
UR - http://www.scopus.com/inward/record.url?scp=85096555028&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/76eae7af-e53a-34cc-9920-17020a9a1d2d/
U2 - 10.1007/s10965-020-02357-1
DO - 10.1007/s10965-020-02357-1
M3 - Article
AN - SCOPUS:85096555028
VL - 27
JO - Journal of Polymer Research
JF - Journal of Polymer Research
SN - 1022-9760
IS - 12
M1 - 384
ER -
ID: 71355339