Hydrodynamic methods and light scattering were used in the studies of solutions of a surface active monomer 11-acryloyloxyundecyltrimethylammonium bromide (AUTA-Br) and its polymers in 0.05 M NaCl. Aqueous solutions of AUTA-Br monomer in the concentration range of 4 to 16 CMC contain individual molecules and near-spherical AUTA-Br aggregates. The pAUTA-Br polymers possess rather high equilibrium rigidity (11.8 nm). This high value of equilibrium rigidity found for pAUTA-Br macromolecules is apparently caused by two factors: the presence of a bulky side substituent in each AUTA-Br monomer unit and incomplete suppression of electrostatic interactions between neighboring monomer units in the backbone.

Original languageEnglish
Article number384
Number of pages12
JournalJournal of Polymer Research
Volume27
Issue number12
DOIs
StatePublished - Dec 2020

    Research areas

  • Polyelectrolyte, Self-assembly, Surfactant monomer

    Scopus subject areas

  • Polymers and Plastics
  • Organic Chemistry
  • Materials Chemistry

ID: 71355339