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Surface active monomers: from micellar solution properties to molecular characteristics. / Lezov, A. A.; Fetin, P. A.; Gubarev, A. S.; Lezova, A. A.; Vezo, O. S.; Senchukova, A. S.; Mikhailova, M. E.; Mikusheva, N. G.; Zorin, I. M.; Tsvetkov, N. V.

в: Journal of Polymer Research, Том 27, № 12, 384, 12.2020.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{601cc0932a7d4fd7b0fb79dbb52eddfb,
title = "Surface active monomers: from micellar solution properties to molecular characteristics",
abstract = "Hydrodynamic methods and light scattering were used in the studies of solutions of a surface active monomer 11-acryloyloxyundecyltrimethylammonium bromide (AUTA-Br) and its polymers in 0.05 M NaCl. Aqueous solutions of AUTA-Br monomer in the concentration range of 4 to 16 CMC contain individual molecules and near-spherical AUTA-Br aggregates. The pAUTA-Br polymers possess rather high equilibrium rigidity (11.8 nm). This high value of equilibrium rigidity found for pAUTA-Br macromolecules is apparently caused by two factors: the presence of a bulky side substituent in each AUTA-Br monomer unit and incomplete suppression of electrostatic interactions between neighboring monomer units in the backbone.",
keywords = "Polyelectrolyte, Self-assembly, Surfactant monomer",
author = "Lezov, {A. A.} and Fetin, {P. A.} and Gubarev, {A. S.} and Lezova, {A. A.} and Vezo, {O. S.} and Senchukova, {A. S.} and Mikhailova, {M. E.} and Mikusheva, {N. G.} and Zorin, {I. M.} and Tsvetkov, {N. V.}",
note = "Funding Information: Lezov, Fetin, Gubarev, Senchukova, Mikusheva and Mikhailova are grateful for the financial support to the Russian Foundation for Basic Research (project № 18–33-20013). The measurements were partially carried out using the instruments of the Analytical Resource Center and Centre for diagnosis of functional materials in medicine, pharmacology and nanoelectronics of Saint‐Petersburg State University. Publisher Copyright: {\textcopyright} 2020, The Polymer Society, Taipei. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",
year = "2020",
month = dec,
doi = "10.1007/s10965-020-02357-1",
language = "English",
volume = "27",
journal = "Journal of Polymer Research",
issn = "1022-9760",
publisher = "Springer Nature",
number = "12",

}

RIS

TY - JOUR

T1 - Surface active monomers: from micellar solution properties to molecular characteristics

AU - Lezov, A. A.

AU - Fetin, P. A.

AU - Gubarev, A. S.

AU - Lezova, A. A.

AU - Vezo, O. S.

AU - Senchukova, A. S.

AU - Mikhailova, M. E.

AU - Mikusheva, N. G.

AU - Zorin, I. M.

AU - Tsvetkov, N. V.

N1 - Funding Information: Lezov, Fetin, Gubarev, Senchukova, Mikusheva and Mikhailova are grateful for the financial support to the Russian Foundation for Basic Research (project № 18–33-20013). The measurements were partially carried out using the instruments of the Analytical Resource Center and Centre for diagnosis of functional materials in medicine, pharmacology and nanoelectronics of Saint‐Petersburg State University. Publisher Copyright: © 2020, The Polymer Society, Taipei. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/12

Y1 - 2020/12

N2 - Hydrodynamic methods and light scattering were used in the studies of solutions of a surface active monomer 11-acryloyloxyundecyltrimethylammonium bromide (AUTA-Br) and its polymers in 0.05 M NaCl. Aqueous solutions of AUTA-Br monomer in the concentration range of 4 to 16 CMC contain individual molecules and near-spherical AUTA-Br aggregates. The pAUTA-Br polymers possess rather high equilibrium rigidity (11.8 nm). This high value of equilibrium rigidity found for pAUTA-Br macromolecules is apparently caused by two factors: the presence of a bulky side substituent in each AUTA-Br monomer unit and incomplete suppression of electrostatic interactions between neighboring monomer units in the backbone.

AB - Hydrodynamic methods and light scattering were used in the studies of solutions of a surface active monomer 11-acryloyloxyundecyltrimethylammonium bromide (AUTA-Br) and its polymers in 0.05 M NaCl. Aqueous solutions of AUTA-Br monomer in the concentration range of 4 to 16 CMC contain individual molecules and near-spherical AUTA-Br aggregates. The pAUTA-Br polymers possess rather high equilibrium rigidity (11.8 nm). This high value of equilibrium rigidity found for pAUTA-Br macromolecules is apparently caused by two factors: the presence of a bulky side substituent in each AUTA-Br monomer unit and incomplete suppression of electrostatic interactions between neighboring monomer units in the backbone.

KW - Polyelectrolyte

KW - Self-assembly

KW - Surfactant monomer

UR - http://www.scopus.com/inward/record.url?scp=85096555028&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/76eae7af-e53a-34cc-9920-17020a9a1d2d/

U2 - 10.1007/s10965-020-02357-1

DO - 10.1007/s10965-020-02357-1

M3 - Article

AN - SCOPUS:85096555028

VL - 27

JO - Journal of Polymer Research

JF - Journal of Polymer Research

SN - 1022-9760

IS - 12

M1 - 384

ER -

ID: 71355339