Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Self-Assembled Supramolecular Complexes with “Rods-in-Belt” Architecture in the Light of Soft X-Rays. / Makarova, A.A.; Grachova, E.V.; Krupenya, D.V.; Vilkov, O.; Fedorov, A.; Usachov, D.; Generalov, A.; Koshevoy, I.O.; Tunik, S.P.; Rühl, E.; Laubschat, C.; Vyalikh, D.V.
в: Journal of Physical Chemistry C, Том 117, № 23, 2013, стр. 12385-12392.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Self-Assembled Supramolecular Complexes with “Rods-in-Belt” Architecture in the Light of Soft X-Rays
AU - Makarova, A.A.
AU - Grachova, E.V.
AU - Krupenya, D.V.
AU - Vilkov, O.
AU - Fedorov, A.
AU - Usachov, D.
AU - Generalov, A.
AU - Koshevoy, I.O.
AU - Tunik, S.P.
AU - Rühl, E.
AU - Laubschat, C.
AU - Vyalikh, D.V.
PY - 2013
Y1 - 2013
N2 - One of the most important properties of the recently discovered “rods-in-belt” supramolecular complexes, containing Au-Cu or Au-Ag cluster core, is the possibility to tune their electronic and photophysical properties through modification of the ligand environment. This opens great perspectives for their applications in light emitting devices and in bio-imaging. The high structural ordering and self-assembling properties of these unique objects may be used to design artificial nanostructures with a complex topology which could become ideal building blocks for next generation electronics. Here we present a detailed experimental study of the electronic structure of the “rods-in-belt” supramolecular complexes. Applying X-ray photoemission and absorption spectroscopy we systematically unravel the structure of their occupied and unoccupied electronic states near the Fermi level. The major contribution to the highest occupied molecular orbitals is made by the triple bonded carbons hosted in the dialkynyl-gold “rods
AB - One of the most important properties of the recently discovered “rods-in-belt” supramolecular complexes, containing Au-Cu or Au-Ag cluster core, is the possibility to tune their electronic and photophysical properties through modification of the ligand environment. This opens great perspectives for their applications in light emitting devices and in bio-imaging. The high structural ordering and self-assembling properties of these unique objects may be used to design artificial nanostructures with a complex topology which could become ideal building blocks for next generation electronics. Here we present a detailed experimental study of the electronic structure of the “rods-in-belt” supramolecular complexes. Applying X-ray photoemission and absorption spectroscopy we systematically unravel the structure of their occupied and unoccupied electronic states near the Fermi level. The major contribution to the highest occupied molecular orbitals is made by the triple bonded carbons hosted in the dialkynyl-gold “rods
U2 - 10.1021/jp404459k
DO - 10.1021/jp404459k
M3 - Article
VL - 117
SP - 12385
EP - 12392
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 23
ER -
ID: 7371140