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Self-Assembled Supramolecular Complexes with “Rods-in-Belt” Architecture in the Light of Soft X-Rays. / Makarova, A.A.; Grachova, E.V.; Krupenya, D.V.; Vilkov, O.; Fedorov, A.; Usachov, D.; Generalov, A.; Koshevoy, I.O.; Tunik, S.P.; Rühl, E.; Laubschat, C.; Vyalikh, D.V.

In: Journal of Physical Chemistry C, Vol. 117, No. 23, 2013, p. 12385-12392.

Research output: Contribution to journal › Article › peer-review

Harvard

Makarova, AA, Grachova, EV, Krupenya, DV, Vilkov, O, Fedorov, A, Usachov, D, Generalov, A, Koshevoy, IO, Tunik, SP, Rühl, E, Laubschat, C & Vyalikh, DV 2013, 'Self-Assembled Supramolecular Complexes with “Rods-in-Belt” Architecture in the Light of Soft X-Rays', Journal of Physical Chemistry C, vol. 117, no. 23, pp. 12385-12392. https://doi.org/10.1021/jp404459k

APA

Makarova, A. A., Grachova, E. V., Krupenya, D. V., Vilkov, O., Fedorov, A., Usachov, D., Generalov, A., Koshevoy, I. O., Tunik, S. P., Rühl, E., Laubschat, C., & Vyalikh, D. V. (2013). Self-Assembled Supramolecular Complexes with “Rods-in-Belt” Architecture in the Light of Soft X-Rays. Journal of Physical Chemistry C, 117(23), 12385-12392. https://doi.org/10.1021/jp404459k

Vancouver

Makarova AA, Grachova EV, Krupenya DV, Vilkov O, Fedorov A, Usachov D et al. Self-Assembled Supramolecular Complexes with “Rods-in-Belt” Architecture in the Light of Soft X-Rays. Journal of Physical Chemistry C. 2013;117(23):12385-12392. https://doi.org/10.1021/jp404459k

Author

Makarova, A.A. ; Grachova, E.V. ; Krupenya, D.V. ; Vilkov, O. ; Fedorov, A. ; Usachov, D. ; Generalov, A. ; Koshevoy, I.O. ; Tunik, S.P. ; Rühl, E. ; Laubschat, C. ; Vyalikh, D.V. / Self-Assembled Supramolecular Complexes with “Rods-in-Belt” Architecture in the Light of Soft X-Rays. In: Journal of Physical Chemistry C. 2013 ; Vol. 117, No. 23. pp. 12385-12392.

BibTeX

@article{f974356f061846afb711376ecc55b82f,
title = "Self-Assembled Supramolecular Complexes with “Rods-in-Belt” Architecture in the Light of Soft X-Rays",
abstract = "One of the most important properties of the recently discovered “rods-in-belt” supramolecular complexes, containing Au-Cu or Au-Ag cluster core, is the possibility to tune their electronic and photophysical properties through modification of the ligand environment. This opens great perspectives for their applications in light emitting devices and in bio-imaging. The high structural ordering and self-assembling properties of these unique objects may be used to design artificial nanostructures with a complex topology which could become ideal building blocks for next generation electronics. Here we present a detailed experimental study of the electronic structure of the “rods-in-belt” supramolecular complexes. Applying X-ray photoemission and absorption spectroscopy we systematically unravel the structure of their occupied and unoccupied electronic states near the Fermi level. The major contribution to the highest occupied molecular orbitals is made by the triple bonded carbons hosted in the dialkynyl-gold “rods",
author = "A.A. Makarova and E.V. Grachova and D.V. Krupenya and O. Vilkov and A. Fedorov and D. Usachov and A. Generalov and I.O. Koshevoy and S.P. Tunik and E. R{\"u}hl and C. Laubschat and D.V. Vyalikh",
year = "2013",
doi = "10.1021/jp404459k",
language = "English",
volume = "117",
pages = "12385--12392",
journal = "Journal of Physical Chemistry C",
issn = "1932-7447",
publisher = "American Chemical Society",
number = "23",

}

RIS

TY - JOUR

T1 - Self-Assembled Supramolecular Complexes with “Rods-in-Belt” Architecture in the Light of Soft X-Rays

AU - Makarova, A.A.

AU - Grachova, E.V.

AU - Krupenya, D.V.

AU - Vilkov, O.

AU - Fedorov, A.

AU - Usachov, D.

AU - Generalov, A.

AU - Koshevoy, I.O.

AU - Tunik, S.P.

AU - Rühl, E.

AU - Laubschat, C.

AU - Vyalikh, D.V.

PY - 2013

Y1 - 2013

N2 - One of the most important properties of the recently discovered “rods-in-belt” supramolecular complexes, containing Au-Cu or Au-Ag cluster core, is the possibility to tune their electronic and photophysical properties through modification of the ligand environment. This opens great perspectives for their applications in light emitting devices and in bio-imaging. The high structural ordering and self-assembling properties of these unique objects may be used to design artificial nanostructures with a complex topology which could become ideal building blocks for next generation electronics. Here we present a detailed experimental study of the electronic structure of the “rods-in-belt” supramolecular complexes. Applying X-ray photoemission and absorption spectroscopy we systematically unravel the structure of their occupied and unoccupied electronic states near the Fermi level. The major contribution to the highest occupied molecular orbitals is made by the triple bonded carbons hosted in the dialkynyl-gold “rods

AB - One of the most important properties of the recently discovered “rods-in-belt” supramolecular complexes, containing Au-Cu or Au-Ag cluster core, is the possibility to tune their electronic and photophysical properties through modification of the ligand environment. This opens great perspectives for their applications in light emitting devices and in bio-imaging. The high structural ordering and self-assembling properties of these unique objects may be used to design artificial nanostructures with a complex topology which could become ideal building blocks for next generation electronics. Here we present a detailed experimental study of the electronic structure of the “rods-in-belt” supramolecular complexes. Applying X-ray photoemission and absorption spectroscopy we systematically unravel the structure of their occupied and unoccupied electronic states near the Fermi level. The major contribution to the highest occupied molecular orbitals is made by the triple bonded carbons hosted in the dialkynyl-gold “rods

U2 - 10.1021/jp404459k

DO - 10.1021/jp404459k

M3 - Article

VL - 117

SP - 12385

EP - 12392

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

SN - 1932-7447

IS - 23

ER -

ID: 7371140