Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Yellowish elongated crystals of the two new compounds Pb 6LaO7-Br (1) and Pb6LaO7Cl (2) have been obtained by the method of solid-state reactions. Both structures can be described in the terms of oxo-centered tetrahedra. The structures of 1 and 2 consist of [O7Pb6La]+ chains that are built from oxocentered OA4 (A = Pb, La) tetrahedra. The halogen ions connect the chains through weak Pb-X bonds. An arrangement of eight OA 4 tetrahedra that all share the same central La atom forms a [O 8Pb10La3]13+ cluster. The clusters are linked into chains, and additional OPb4 tetrahedra are attached to the chains. Incorporation of Cl atoms instead of Br atoms into the structure causes a lowering of the symmetry from Cmcm to C2/m.
| Язык оригинала | английский |
|---|---|
| Страницы (с-по) | 1523-1525 |
| Число страниц | 3 |
| Журнал | Inorganic Chemistry |
| Том | 46 |
| Номер выпуска | 5 |
| DOI | |
| Состояние | Опубликовано - 5 мар 2007 |
ID: 9145919