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Lead rare-earth oxyhalides : Syntheses and characterization of Pb 6LaO7X (X = Cl, Br). / Siidra, Oleg I.; Krivovichev, Sergey V.; Armbruster, Thomas; Depmeier, Wulf.

в: Inorganic Chemistry, Том 46, № 5, 05.03.2007, стр. 1523-1525.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Siidra, OI, Krivovichev, SV, Armbruster, T & Depmeier, W 2007, 'Lead rare-earth oxyhalides: Syntheses and characterization of Pb 6LaO7X (X = Cl, Br)', Inorganic Chemistry, Том. 46, № 5, стр. 1523-1525. https://doi.org/10.1021/ic062191y

APA

Vancouver

Author

Siidra, Oleg I. ; Krivovichev, Sergey V. ; Armbruster, Thomas ; Depmeier, Wulf. / Lead rare-earth oxyhalides : Syntheses and characterization of Pb 6LaO7X (X = Cl, Br). в: Inorganic Chemistry. 2007 ; Том 46, № 5. стр. 1523-1525.

BibTeX

@article{9e123bad45fc4690ae183dc16f9a78c2,
title = "Lead rare-earth oxyhalides: Syntheses and characterization of Pb 6LaO7X (X = Cl, Br)",
abstract = "Yellowish elongated crystals of the two new compounds Pb 6LaO7-Br (1) and Pb6LaO7Cl (2) have been obtained by the method of solid-state reactions. Both structures can be described in the terms of oxo-centered tetrahedra. The structures of 1 and 2 consist of [O7Pb6La]+ chains that are built from oxocentered OA4 (A = Pb, La) tetrahedra. The halogen ions connect the chains through weak Pb-X bonds. An arrangement of eight OA 4 tetrahedra that all share the same central La atom forms a [O 8Pb10La3]13+ cluster. The clusters are linked into chains, and additional OPb4 tetrahedra are attached to the chains. Incorporation of Cl atoms instead of Br atoms into the structure causes a lowering of the symmetry from Cmcm to C2/m.",
author = "Siidra, {Oleg I.} and Krivovichev, {Sergey V.} and Thomas Armbruster and Wulf Depmeier",
year = "2007",
month = mar,
day = "5",
doi = "10.1021/ic062191y",
language = "English",
volume = "46",
pages = "1523--1525",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "5",

}

RIS

TY - JOUR

T1 - Lead rare-earth oxyhalides

T2 - Syntheses and characterization of Pb 6LaO7X (X = Cl, Br)

AU - Siidra, Oleg I.

AU - Krivovichev, Sergey V.

AU - Armbruster, Thomas

AU - Depmeier, Wulf

PY - 2007/3/5

Y1 - 2007/3/5

N2 - Yellowish elongated crystals of the two new compounds Pb 6LaO7-Br (1) and Pb6LaO7Cl (2) have been obtained by the method of solid-state reactions. Both structures can be described in the terms of oxo-centered tetrahedra. The structures of 1 and 2 consist of [O7Pb6La]+ chains that are built from oxocentered OA4 (A = Pb, La) tetrahedra. The halogen ions connect the chains through weak Pb-X bonds. An arrangement of eight OA 4 tetrahedra that all share the same central La atom forms a [O 8Pb10La3]13+ cluster. The clusters are linked into chains, and additional OPb4 tetrahedra are attached to the chains. Incorporation of Cl atoms instead of Br atoms into the structure causes a lowering of the symmetry from Cmcm to C2/m.

AB - Yellowish elongated crystals of the two new compounds Pb 6LaO7-Br (1) and Pb6LaO7Cl (2) have been obtained by the method of solid-state reactions. Both structures can be described in the terms of oxo-centered tetrahedra. The structures of 1 and 2 consist of [O7Pb6La]+ chains that are built from oxocentered OA4 (A = Pb, La) tetrahedra. The halogen ions connect the chains through weak Pb-X bonds. An arrangement of eight OA 4 tetrahedra that all share the same central La atom forms a [O 8Pb10La3]13+ cluster. The clusters are linked into chains, and additional OPb4 tetrahedra are attached to the chains. Incorporation of Cl atoms instead of Br atoms into the structure causes a lowering of the symmetry from Cmcm to C2/m.

UR - http://www.scopus.com/inward/record.url?scp=33947377791&partnerID=8YFLogxK

U2 - 10.1021/ic062191y

DO - 10.1021/ic062191y

M3 - Article

C2 - 17266304

AN - SCOPUS:33947377791

VL - 46

SP - 1523

EP - 1525

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 5

ER -

ID: 9145919