Research output: Contribution to journal › Article › peer-review
Yellowish elongated crystals of the two new compounds Pb 6LaO7-Br (1) and Pb6LaO7Cl (2) have been obtained by the method of solid-state reactions. Both structures can be described in the terms of oxo-centered tetrahedra. The structures of 1 and 2 consist of [O7Pb6La]+ chains that are built from oxocentered OA4 (A = Pb, La) tetrahedra. The halogen ions connect the chains through weak Pb-X bonds. An arrangement of eight OA 4 tetrahedra that all share the same central La atom forms a [O 8Pb10La3]13+ cluster. The clusters are linked into chains, and additional OPb4 tetrahedra are attached to the chains. Incorporation of Cl atoms instead of Br atoms into the structure causes a lowering of the symmetry from Cmcm to C2/m.
| Original language | English |
|---|---|
| Pages (from-to) | 1523-1525 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry |
| Volume | 46 |
| Issue number | 5 |
| DOIs | |
| State | Published - 5 Mar 2007 |
ID: 9145919