DOI

An overview is given of results complementing the theory of an equation of state based on the excluded volume in three directions: generalizing the form of an equation of state with respect to long-range forces; computing the equation-of-state parameters in a multicomponent system at arbitrary particle size ratios; reformulating the theory in terms of reduced density. The theory based on the excluded volume does not touch upon long-range forces, but they should be taken in a specific form of the complete analysis of an equation of state. The theory based on the excluded volume does not yield a unique equation of state for all densities, but suggests separately an equation of state of a type for a condensed matter and an equation of state of a type for a fluid state, both of good accuracy.

Язык оригиналаанглийский
Страницы (с-по)10268-10273
Число страниц6
ЖурналJournal of Chemical Physics
Том119
Номер выпуска19
DOI
СостояниеОпубликовано - 15 ноя 2003

    Предметные области Scopus

  • Физика и астрономия (все)
  • Физическая и теоретическая химия

ID: 95702655