Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Generalized equation of state and exclusion factor for multicomponent systems. / Rusanov, Anatoly I.
в: Journal of Chemical Physics, Том 119, № 19, 15.11.2003, стр. 10268-10273.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Generalized equation of state and exclusion factor for multicomponent systems
AU - Rusanov, Anatoly I.
PY - 2003/11/15
Y1 - 2003/11/15
N2 - An overview is given of results complementing the theory of an equation of state based on the excluded volume in three directions: generalizing the form of an equation of state with respect to long-range forces; computing the equation-of-state parameters in a multicomponent system at arbitrary particle size ratios; reformulating the theory in terms of reduced density. The theory based on the excluded volume does not touch upon long-range forces, but they should be taken in a specific form of the complete analysis of an equation of state. The theory based on the excluded volume does not yield a unique equation of state for all densities, but suggests separately an equation of state of a type for a condensed matter and an equation of state of a type for a fluid state, both of good accuracy.
AB - An overview is given of results complementing the theory of an equation of state based on the excluded volume in three directions: generalizing the form of an equation of state with respect to long-range forces; computing the equation-of-state parameters in a multicomponent system at arbitrary particle size ratios; reformulating the theory in terms of reduced density. The theory based on the excluded volume does not touch upon long-range forces, but they should be taken in a specific form of the complete analysis of an equation of state. The theory based on the excluded volume does not yield a unique equation of state for all densities, but suggests separately an equation of state of a type for a condensed matter and an equation of state of a type for a fluid state, both of good accuracy.
UR - http://www.scopus.com/inward/record.url?scp=0344667448&partnerID=8YFLogxK
U2 - 10.1063/1.1618732
DO - 10.1063/1.1618732
M3 - Article
AN - SCOPUS:0344667448
VL - 119
SP - 10268
EP - 10273
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 19
ER -
ID: 95702655