DOI

Abstract: Reaction of the Lewis acid Ga[N(C6F5)2]3 with acetonitrile and pyridine in toluene solution was characterized by 19F NMR. Quantum chemical calculations show that the shorter donor-acceptor bond in the acetonitrile complex is weaker by 73 kJ/mol than the longer donor-acceptor bond in the pyridine complex, which is consistent with partial dissociation of the Ga[N(C6F5)2]3·MeCN complex in toluene.

Язык оригиналаанглийский
Страницы (с-по)2305-2311
Число страниц7
ЖурналRussian Journal of General Chemistry
Том90
Номер выпуска12
DOI
СостояниеОпубликовано - дек 2020

    Предметные области Scopus

  • Химия (все)

ID: 74538128