Research output: Contribution to journal › Article › peer-review
Abstract: Reaction of the Lewis acid Ga[N(C6F5)2]3 with acetonitrile and pyridine in toluene solution was characterized by 19F NMR. Quantum chemical calculations show that the shorter donor-acceptor bond in the acetonitrile complex is weaker by 73 kJ/mol than the longer donor-acceptor bond in the pyridine complex, which is consistent with partial dissociation of the Ga[N(C6F5)2]3·MeCN complex in toluene.
| Original language | English |
|---|---|
| Pages (from-to) | 2305-2311 |
| Number of pages | 7 |
| Journal | Russian Journal of General Chemistry |
| Volume | 90 |
| Issue number | 12 |
| DOIs | |
| State | Published - Dec 2020 |
ID: 74538128