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Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Acetonitrile and Pyridine. / Zavgorodnii, A. S.; Pomogaeva, V.; Timoshkin, A. Y.

в: Russian Journal of General Chemistry, Том 90, № 12, 12.2020, стр. 2305-2311.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Zavgorodnii, AS, Pomogaeva, V & Timoshkin, AY 2020, 'Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Acetonitrile and Pyridine', Russian Journal of General Chemistry, Том. 90, № 12, стр. 2305-2311. https://doi.org/10.1134/S1070363220120130

APA

Zavgorodnii, A. S., Pomogaeva, V., & Timoshkin, A. Y. (2020). Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Acetonitrile and Pyridine. Russian Journal of General Chemistry, 90(12), 2305-2311. https://doi.org/10.1134/S1070363220120130

Vancouver

Zavgorodnii AS, Pomogaeva V, Timoshkin AY. Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Acetonitrile and Pyridine. Russian Journal of General Chemistry. 2020 Дек.;90(12):2305-2311. https://doi.org/10.1134/S1070363220120130

Author

Zavgorodnii, A. S. ; Pomogaeva, V. ; Timoshkin, A. Y. / Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Acetonitrile and Pyridine. в: Russian Journal of General Chemistry. 2020 ; Том 90, № 12. стр. 2305-2311.

BibTeX

@article{3a95a734914c4b2aa689ff7e04d4d9a0,
title = "Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Acetonitrile and Pyridine",
abstract = "Abstract: Reaction of the Lewis acid Ga[N(C6F5)2]3 with acetonitrile and pyridine in toluene solution was characterized by 19F NMR. Quantum chemical calculations show that the shorter donor-acceptor bond in the acetonitrile complex is weaker by 73 kJ/mol than the longer donor-acceptor bond in the pyridine complex, which is consistent with partial dissociation of the Ga[N(C6F5)2]3·MeCN complex in toluene.",
keywords = "acetonitrile, donor-acceptor complex, gallium decafluorodiphenylamide, pyridine, quantum chemical computations",
author = "Zavgorodnii, {A. S.} and V. Pomogaeva and Timoshkin, {A. Y.}",
note = "Funding Information: The work was supported by the Russian science Foundation (grant no. 18-13-00196) using equipment from the Computing center of St. Petersburg state University and the Chemistry center of the University of Bremen (UBS-Zentrum f{\"u}r Chemie). Publisher Copyright: {\textcopyright} 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2020",
month = dec,
doi = "10.1134/S1070363220120130",
language = "English",
volume = "90",
pages = "2305--2311",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "12",

}

RIS

TY - JOUR

T1 - Complexes of the Lewis Acid Ga[N(C6F5)2]3 with Acetonitrile and Pyridine

AU - Zavgorodnii, A. S.

AU - Pomogaeva, V.

AU - Timoshkin, A. Y.

N1 - Funding Information: The work was supported by the Russian science Foundation (grant no. 18-13-00196) using equipment from the Computing center of St. Petersburg state University and the Chemistry center of the University of Bremen (UBS-Zentrum für Chemie). Publisher Copyright: © 2020, Pleiades Publishing, Ltd. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2020/12

Y1 - 2020/12

N2 - Abstract: Reaction of the Lewis acid Ga[N(C6F5)2]3 with acetonitrile and pyridine in toluene solution was characterized by 19F NMR. Quantum chemical calculations show that the shorter donor-acceptor bond in the acetonitrile complex is weaker by 73 kJ/mol than the longer donor-acceptor bond in the pyridine complex, which is consistent with partial dissociation of the Ga[N(C6F5)2]3·MeCN complex in toluene.

AB - Abstract: Reaction of the Lewis acid Ga[N(C6F5)2]3 with acetonitrile and pyridine in toluene solution was characterized by 19F NMR. Quantum chemical calculations show that the shorter donor-acceptor bond in the acetonitrile complex is weaker by 73 kJ/mol than the longer donor-acceptor bond in the pyridine complex, which is consistent with partial dissociation of the Ga[N(C6F5)2]3·MeCN complex in toluene.

KW - acetonitrile

KW - donor-acceptor complex

KW - gallium decafluorodiphenylamide

KW - pyridine

KW - quantum chemical computations

UR - http://www.scopus.com/inward/record.url?scp=85100586853&partnerID=8YFLogxK

U2 - 10.1134/S1070363220120130

DO - 10.1134/S1070363220120130

M3 - Article

AN - SCOPUS:85100586853

VL - 90

SP - 2305

EP - 2311

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 12

ER -

ID: 74538128