Experimental data [1] on the Hartley band of ozone absorption at temperatures T = 300, 500, 720, and 900 K were analyzed with the aim of refining the parameters of the potential surface of the excited electronic state and of the electronic transition-moment function. The analysis was carried out using a fitting procedure in the framework of the method of spectral moments. The excited-state potential was assumed to contain the quartic-anharmonicity terms in the coordinate corresponding to the antisymmetric (repulsive) mode; the electronic transition moment was assumed to depend on the deformation coordinate, and the Dushinskii effect was incorporated as a cross term between the symmetric and deformation modes. The resulting band contours were reproduced with an accuracy comparable to the experimental accuracy [1].

Язык оригиналаанглийский
Страницы (с-по)28-31
Число страниц4
ЖурналOptics and Spectroscopy (English translation of Optika i Spektroskopiya)
Том77
Номер выпуска1
СостояниеОпубликовано - 1 июл 1994

    Предметные области Scopus

  • Спектроскопия
  • Атомная и молекулярная физика и оптика

ID: 38480214