Analysis of dissociative absorption of polyatomic molecules by the method of spectral moments

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Analysis of dissociative absorption of polyatomic molecules by the method of spectral moments : the Hartley band of the ozone molecule. / Ivanov, V. S.; Sovkov, V. B.; Garbaruk, V. V.

в: Optics and Spectroscopy (English translation of Optika i Spektroskopiya), Том 77, № 1, 01.07.1994, стр. 28-31.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Author

Ivanov, V. S. ; Sovkov, V. B. ; Garbaruk, V. V. / Analysis of dissociative absorption of polyatomic molecules by the method of spectral moments : the Hartley band of the ozone molecule. в: Optics and Spectroscopy (English translation of Optika i Spektroskopiya). 1994 ; Том 77, № 1. стр. 28-31.

BibTeX

@article{ac8bcec4fe6e44efa5fcc2e15aca8440,

title = "Analysis of dissociative absorption of polyatomic molecules by the method of spectral moments: the Hartley band of the ozone molecule",

abstract = "Experimental data [1] on the Hartley band of ozone absorption at temperatures T = 300, 500, 720, and 900 K were analyzed with the aim of refining the parameters of the potential surface of the excited electronic state and of the electronic transition-moment function. The analysis was carried out using a fitting procedure in the framework of the method of spectral moments. The excited-state potential was assumed to contain the quartic-anharmonicity terms in the coordinate corresponding to the antisymmetric (repulsive) mode; the electronic transition moment was assumed to depend on the deformation coordinate, and the Dushinskii effect was incorporated as a cross term between the symmetric and deformation modes. The resulting band contours were reproduced with an accuracy comparable to the experimental accuracy [1].",

author = "Ivanov, {V. S.} and Sovkov, {V. B.} and Garbaruk, {V. V.}",

year = "1994",

month = jul,

day = "1",

language = "English",

volume = "77",

pages = "28--31",

journal = "OPTICS AND SPECTROSCOPY",

issn = "0030-400X",

publisher = "Pleiades Publishing",

number = "1",

}

RIS

TY - JOUR

T1 - Analysis of dissociative absorption of polyatomic molecules by the method of spectral moments

T2 - the Hartley band of the ozone molecule

AU - Ivanov, V. S.

AU - Sovkov, V. B.

AU - Garbaruk, V. V.

PY - 1994/7/1

Y1 - 1994/7/1

N2 - Experimental data [1] on the Hartley band of ozone absorption at temperatures T = 300, 500, 720, and 900 K were analyzed with the aim of refining the parameters of the potential surface of the excited electronic state and of the electronic transition-moment function. The analysis was carried out using a fitting procedure in the framework of the method of spectral moments. The excited-state potential was assumed to contain the quartic-anharmonicity terms in the coordinate corresponding to the antisymmetric (repulsive) mode; the electronic transition moment was assumed to depend on the deformation coordinate, and the Dushinskii effect was incorporated as a cross term between the symmetric and deformation modes. The resulting band contours were reproduced with an accuracy comparable to the experimental accuracy [1].

AB - Experimental data [1] on the Hartley band of ozone absorption at temperatures T = 300, 500, 720, and 900 K were analyzed with the aim of refining the parameters of the potential surface of the excited electronic state and of the electronic transition-moment function. The analysis was carried out using a fitting procedure in the framework of the method of spectral moments. The excited-state potential was assumed to contain the quartic-anharmonicity terms in the coordinate corresponding to the antisymmetric (repulsive) mode; the electronic transition moment was assumed to depend on the deformation coordinate, and the Dushinskii effect was incorporated as a cross term between the symmetric and deformation modes. The resulting band contours were reproduced with an accuracy comparable to the experimental accuracy [1].

UR - http://www.scopus.com/inward/record.url?scp=0028463981&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0028463981

VL - 77

SP - 28

EP - 31

JO - OPTICS AND SPECTROSCOPY

JF - OPTICS AND SPECTROSCOPY

SN - 0030-400X

IS - 1

ER -

ID: 38480214