Research output: Contribution to journal › Article › peer-review
Experimental data [1] on the Hartley band of ozone absorption at temperatures T = 300, 500, 720, and 900 K were analyzed with the aim of refining the parameters of the potential surface of the excited electronic state and of the electronic transition-moment function. The analysis was carried out using a fitting procedure in the framework of the method of spectral moments. The excited-state potential was assumed to contain the quartic-anharmonicity terms in the coordinate corresponding to the antisymmetric (repulsive) mode; the electronic transition moment was assumed to depend on the deformation coordinate, and the Dushinskii effect was incorporated as a cross term between the symmetric and deformation modes. The resulting band contours were reproduced with an accuracy comparable to the experimental accuracy [1].
Original language | English |
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Pages (from-to) | 28-31 |
Number of pages | 4 |
Journal | Optics and Spectroscopy (English translation of Optika i Spektroskopiya) |
Volume | 77 |
Issue number | 1 |
State | Published - 1 Jul 1994 |
ID: 38480214