Thermodynamic and thermal properties of the C60-L-lysine derivative

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Thermodynamic and thermal properties of the C₆₀-L-lysine derivative. / Lelet, Maxim I.; Semenov, Konstantin N.; Andrusenko, Elena V.; Charykov, Nikolay A.; Murin, Igor V.

In: Journal of Chemical Thermodynamics, Vol. 115, 2017, p. 7-11.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{e30c4a4b7f6b43b5846fcd7858a5bae7,

title = "Thermodynamic and thermal properties of the C60-L-lysine derivative",

abstract = "In the present research, the low-temperature molar heat capacity, Cp,m°, of C60 – L-lysine derivative was measured using adiabatic calorimetry from T = 13 K to T = 326 K. The respective molar third law entropy at T = 298.15 K, Sm°, was calculated giving (1110 ± 3) J·K−1·mol−1 for C60 – L-lysine derivative. Smoothed Cp,m°(T) values between T → 0 K and 320 K are presented along with the values for Sm° and the functions [Hm°(T) – Hm°(0)] and [Gm°(T) – Hm°(0)]. The standard molar entropy of formation, ΔfSm°, at T = 298.15 K was calculated for the compound under study in the crystalline state giving −1916 ± 5 J·K−1·mol−1. The complex thermal analysis of the C60-Lys crystallohydrate was performed from T = 300 to T = 1323 K.",

keywords = "Enthalpy, Entropy, Fullerene, Gibbs function, Heat capacity, L-lysine",

author = "Lelet, {Maxim I.} and Semenov, {Konstantin N.} and Andrusenko, {Elena V.} and Charykov, {Nikolay A.} and Murin, {Igor V.}",

note = "Publisher Copyright: {\textcopyright} 2017 Elsevier Ltd",

year = "2017",

doi = "10.1016/j.jct.2017.07.017",

language = "English",

volume = "115",

pages = "7--11",

journal = "Journal of Chemical Thermodynamics",

issn = "0021-9614",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Thermodynamic and thermal properties of the C60-L-lysine derivative

AU - Lelet, Maxim I.

AU - Semenov, Konstantin N.

AU - Andrusenko, Elena V.

AU - Charykov, Nikolay A.

AU - Murin, Igor V.

PY - 2017

Y1 - 2017

N2 - In the present research, the low-temperature molar heat capacity, Cp,m°, of C60 – L-lysine derivative was measured using adiabatic calorimetry from T = 13 K to T = 326 K. The respective molar third law entropy at T = 298.15 K, Sm°, was calculated giving (1110 ± 3) J·K−1·mol−1 for C60 – L-lysine derivative. Smoothed Cp,m°(T) values between T → 0 K and 320 K are presented along with the values for Sm° and the functions [Hm°(T) – Hm°(0)] and [Gm°(T) – Hm°(0)]. The standard molar entropy of formation, ΔfSm°, at T = 298.15 K was calculated for the compound under study in the crystalline state giving −1916 ± 5 J·K−1·mol−1. The complex thermal analysis of the C60-Lys crystallohydrate was performed from T = 300 to T = 1323 K.

AB - In the present research, the low-temperature molar heat capacity, Cp,m°, of C60 – L-lysine derivative was measured using adiabatic calorimetry from T = 13 K to T = 326 K. The respective molar third law entropy at T = 298.15 K, Sm°, was calculated giving (1110 ± 3) J·K−1·mol−1 for C60 – L-lysine derivative. Smoothed Cp,m°(T) values between T → 0 K and 320 K are presented along with the values for Sm° and the functions [Hm°(T) – Hm°(0)] and [Gm°(T) – Hm°(0)]. The standard molar entropy of formation, ΔfSm°, at T = 298.15 K was calculated for the compound under study in the crystalline state giving −1916 ± 5 J·K−1·mol−1. The complex thermal analysis of the C60-Lys crystallohydrate was performed from T = 300 to T = 1323 K.

KW - Enthalpy

KW - Entropy

KW - Fullerene

KW - Gibbs function

KW - Heat capacity

KW - L-lysine

UR - http://www.scopus.com/inward/record.url?scp=85024866799&partnerID=8YFLogxK

U2 - 10.1016/j.jct.2017.07.017

DO - 10.1016/j.jct.2017.07.017

M3 - Article

VL - 115

SP - 7

EP - 11

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

SN - 0021-9614

ER -

ID: 13343962