Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thermodynamic and thermal properties of the C60-L-lysine derivative. / Lelet, Maxim I.; Semenov, Konstantin N.; Andrusenko, Elena V.; Charykov, Nikolay A.; Murin, Igor V.
в: Journal of Chemical Thermodynamics, Том 115, 2017, стр. 7-11.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Thermodynamic and thermal properties of the C60-L-lysine derivative
AU - Lelet, Maxim I.
AU - Semenov, Konstantin N.
AU - Andrusenko, Elena V.
AU - Charykov, Nikolay A.
AU - Murin, Igor V.
N1 - Publisher Copyright: © 2017 Elsevier Ltd
PY - 2017
Y1 - 2017
N2 - In the present research, the low-temperature molar heat capacity, Cp,m°, of C60 – L-lysine derivative was measured using adiabatic calorimetry from T = 13 K to T = 326 K. The respective molar third law entropy at T = 298.15 K, Sm°, was calculated giving (1110 ± 3) J·K−1·mol−1 for C60 – L-lysine derivative. Smoothed Cp,m°(T) values between T → 0 K and 320 K are presented along with the values for Sm° and the functions [Hm°(T) – Hm°(0)] and [Gm°(T) – Hm°(0)]. The standard molar entropy of formation, ΔfSm°, at T = 298.15 K was calculated for the compound under study in the crystalline state giving −1916 ± 5 J·K−1·mol−1. The complex thermal analysis of the C60-Lys crystallohydrate was performed from T = 300 to T = 1323 K.
AB - In the present research, the low-temperature molar heat capacity, Cp,m°, of C60 – L-lysine derivative was measured using adiabatic calorimetry from T = 13 K to T = 326 K. The respective molar third law entropy at T = 298.15 K, Sm°, was calculated giving (1110 ± 3) J·K−1·mol−1 for C60 – L-lysine derivative. Smoothed Cp,m°(T) values between T → 0 K and 320 K are presented along with the values for Sm° and the functions [Hm°(T) – Hm°(0)] and [Gm°(T) – Hm°(0)]. The standard molar entropy of formation, ΔfSm°, at T = 298.15 K was calculated for the compound under study in the crystalline state giving −1916 ± 5 J·K−1·mol−1. The complex thermal analysis of the C60-Lys crystallohydrate was performed from T = 300 to T = 1323 K.
KW - Enthalpy
KW - Entropy
KW - Fullerene
KW - Gibbs function
KW - Heat capacity
KW - L-lysine
UR - http://www.scopus.com/inward/record.url?scp=85024866799&partnerID=8YFLogxK
U2 - 10.1016/j.jct.2017.07.017
DO - 10.1016/j.jct.2017.07.017
M3 - Article
VL - 115
SP - 7
EP - 11
JO - Journal of Chemical Thermodynamics
JF - Journal of Chemical Thermodynamics
SN - 0021-9614
ER -
ID: 13343962