Research output: Contribution to journal › Conference article › peer-review
The stretching-mode (SM) absorption of isolated SeH- or SeD- molecular defects in alkalihalides show a resolved spectral structure due to the different reduced masses of the six natural stable Se isotopes. In a FTIR study of these defects in KCl and KBr, we have observed new SM absorptions of defect pairs which scale quadratically with the defect concentration. For `equal pairs' SeH- -SeH- and SeD- -SeD-, the fundamental SM absorption shows (in contrast to `mixed' SeH- -ScD- pairs) a distinctly different Se-isotope splitting, while the overtone splitting of all pairs remains similar to that of the isolated defects. Besides a simple classical coupled-oscillator treatment, we present a quantum-mechanical calculation, explaining the observed spectral behavior by resonance interaction of the molecules in pairs of equal (or `nearly equal') frequencies.
Original language | English |
---|---|
Pages (from-to) | 311-315 |
Number of pages | 5 |
Journal | Radiation Effects and Defects in Solids |
Volume | 151 |
Issue number | 1 |
DOIs | |
State | Published - 1999 |
Event | Proceedings of the 1998 8th Europhysical Conference on Defects in Insulating Materials, EURODIM 98 - Keele, UK Duration: 6 Jun 1998 → 11 Jun 1998 |
ID: 90572163