The stretching-mode (SM) absorption of isolated SeH- or SeD- molecular defects in alkalihalides show a resolved spectral structure due to the different reduced masses of the six natural stable Se isotopes. In a FTIR study of these defects in KCl and KBr, we have observed new SM absorptions of defect pairs which scale quadratically with the defect concentration. For `equal pairs' SeH- -SeH- and SeD- -SeD-, the fundamental SM absorption shows (in contrast to `mixed' SeH- -ScD- pairs) a distinctly different Se-isotope splitting, while the overtone splitting of all pairs remains similar to that of the isolated defects. Besides a simple classical coupled-oscillator treatment, we present a quantum-mechanical calculation, explaining the observed spectral behavior by resonance interaction of the molecules in pairs of equal (or `nearly equal') frequencies.

Original languageEnglish
Pages (from-to)311-315
Number of pages5
JournalRadiation Effects and Defects in Solids
Volume151
Issue number1
DOIs
StatePublished - 1999
EventProceedings of the 1998 8th Europhysical Conference on Defects in Insulating Materials, EURODIM 98 - Keele, UK
Duration: 6 Jun 199811 Jun 1998

    Scopus subject areas

  • Radiation
  • Nuclear and High Energy Physics
  • Materials Science(all)
  • Condensed Matter Physics

ID: 90572163