DOI

The stretching-mode (SM) absorption of isolated SeH- or SeD- molecular defects in alkalihalides show a resolved spectral structure due to the different reduced masses of the six natural stable Se isotopes. In a FTIR study of these defects in KCl and KBr, we have observed new SM absorptions of defect pairs which scale quadratically with the defect concentration. For `equal pairs' SeH- -SeH- and SeD- -SeD-, the fundamental SM absorption shows (in contrast to `mixed' SeH- -ScD- pairs) a distinctly different Se-isotope splitting, while the overtone splitting of all pairs remains similar to that of the isolated defects. Besides a simple classical coupled-oscillator treatment, we present a quantum-mechanical calculation, explaining the observed spectral behavior by resonance interaction of the molecules in pairs of equal (or `nearly equal') frequencies.

Язык оригиналаанглийский
Страницы (с-по)311-315
Число страниц5
ЖурналRadiation Effects and Defects in Solids
Том151
Номер выпуска1
DOI
СостояниеОпубликовано - 1999
СобытиеProceedings of the 1998 8th Europhysical Conference on Defects in Insulating Materials, EURODIM 98 - Keele, UK
Продолжительность: 6 июн 199811 июн 1998

    Предметные области Scopus

  • Радиация
  • Ядерная физика и физика высоких энергий
  • Материаловедение (все)
  • Физика конденсатов

ID: 90572163