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Stretching mode interaction of equal and unequal pairs of SeH- and SeD- defects in alkali halides. / Afanasiev, A. D.; Ivanov, A. A.; Luty, Fritz; Melikova, S. M.; Shchepkin, D. N.

In: Radiation Effects and Defects in Solids, Vol. 151, No. 1, 1999, p. 311-315.

Research output: Contribution to journal › Conference article › peer-review

Harvard

Afanasiev, AD, Ivanov, AA, Luty, F, Melikova, SM & Shchepkin, DN 1999, 'Stretching mode interaction of equal and unequal pairs of SeH- and SeD- defects in alkali halides', Radiation Effects and Defects in Solids, vol. 151, no. 1, pp. 311-315. https://doi.org/10.1080/10420159908245973

APA

Afanasiev, A. D., Ivanov, A. A., Luty, F., Melikova, S. M., & Shchepkin, D. N. (1999). Stretching mode interaction of equal and unequal pairs of SeH- and SeD- defects in alkali halides. Radiation Effects and Defects in Solids, 151(1), 311-315. https://doi.org/10.1080/10420159908245973

Vancouver

Afanasiev AD, Ivanov AA, Luty F, Melikova SM, Shchepkin DN. Stretching mode interaction of equal and unequal pairs of SeH- and SeD- defects in alkali halides. Radiation Effects and Defects in Solids. 1999;151(1):311-315. https://doi.org/10.1080/10420159908245973

Author

Afanasiev, A. D. ; Ivanov, A. A. ; Luty, Fritz ; Melikova, S. M. ; Shchepkin, D. N. / Stretching mode interaction of equal and unequal pairs of SeH- and SeD- defects in alkali halides. In: Radiation Effects and Defects in Solids. 1999 ; Vol. 151, No. 1. pp. 311-315.

BibTeX

@article{162d4852d3e04ef686da2d9b5e50b489,
title = "Stretching mode interaction of equal and unequal pairs of SeH- and SeD- defects in alkali halides",
abstract = "The stretching-mode (SM) absorption of isolated SeH- or SeD- molecular defects in alkalihalides show a resolved spectral structure due to the different reduced masses of the six natural stable Se isotopes. In a FTIR study of these defects in KCl and KBr, we have observed new SM absorptions of defect pairs which scale quadratically with the defect concentration. For `equal pairs' SeH- -SeH- and SeD- -SeD-, the fundamental SM absorption shows (in contrast to `mixed' SeH- -ScD- pairs) a distinctly different Se-isotope splitting, while the overtone splitting of all pairs remains similar to that of the isolated defects. Besides a simple classical coupled-oscillator treatment, we present a quantum-mechanical calculation, explaining the observed spectral behavior by resonance interaction of the molecules in pairs of equal (or `nearly equal') frequencies.",
author = "Afanasiev, {A. D.} and Ivanov, {A. A.} and Fritz Luty and Melikova, {S. M.} and Shchepkin, {D. N.}",
year = "1999",
doi = "10.1080/10420159908245973",
language = "English",
volume = "151",
pages = "311--315",
journal = "Radiation Effects and Defects in Solids",
issn = "1042-0150",
publisher = "Taylor & Francis",
number = "1",
note = "Proceedings of the 1998 8th Europhysical Conference on Defects in Insulating Materials, EURODIM 98 ; Conference date: 06-06-1998 Through 11-06-1998",

}

RIS

TY - JOUR

T1 - Stretching mode interaction of equal and unequal pairs of SeH- and SeD- defects in alkali halides

AU - Afanasiev, A. D.

AU - Ivanov, A. A.

AU - Luty, Fritz

AU - Melikova, S. M.

AU - Shchepkin, D. N.

PY - 1999

Y1 - 1999

N2 - The stretching-mode (SM) absorption of isolated SeH- or SeD- molecular defects in alkalihalides show a resolved spectral structure due to the different reduced masses of the six natural stable Se isotopes. In a FTIR study of these defects in KCl and KBr, we have observed new SM absorptions of defect pairs which scale quadratically with the defect concentration. For `equal pairs' SeH- -SeH- and SeD- -SeD-, the fundamental SM absorption shows (in contrast to `mixed' SeH- -ScD- pairs) a distinctly different Se-isotope splitting, while the overtone splitting of all pairs remains similar to that of the isolated defects. Besides a simple classical coupled-oscillator treatment, we present a quantum-mechanical calculation, explaining the observed spectral behavior by resonance interaction of the molecules in pairs of equal (or `nearly equal') frequencies.

AB - The stretching-mode (SM) absorption of isolated SeH- or SeD- molecular defects in alkalihalides show a resolved spectral structure due to the different reduced masses of the six natural stable Se isotopes. In a FTIR study of these defects in KCl and KBr, we have observed new SM absorptions of defect pairs which scale quadratically with the defect concentration. For `equal pairs' SeH- -SeH- and SeD- -SeD-, the fundamental SM absorption shows (in contrast to `mixed' SeH- -ScD- pairs) a distinctly different Se-isotope splitting, while the overtone splitting of all pairs remains similar to that of the isolated defects. Besides a simple classical coupled-oscillator treatment, we present a quantum-mechanical calculation, explaining the observed spectral behavior by resonance interaction of the molecules in pairs of equal (or `nearly equal') frequencies.

UR - http://www.scopus.com/inward/record.url?scp=0033281626&partnerID=8YFLogxK

U2 - 10.1080/10420159908245973

DO - 10.1080/10420159908245973

M3 - Conference article

AN - SCOPUS:0033281626

VL - 151

SP - 311

EP - 315

JO - Radiation Effects and Defects in Solids

JF - Radiation Effects and Defects in Solids

SN - 1042-0150

IS - 1

T2 - Proceedings of the 1998 8th Europhysical Conference on Defects in Insulating Materials, EURODIM 98

Y2 - 6 June 1998 through 11 June 1998

ER -

ID: 90572163