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Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 - (2,6-diisopropylphenyl)diazabutadiene system. / Kraikivskii, Peter B.; Saraev, Vitaly V.; Bocharova, Victoria V.; Romanenko, Galina V.; Petrovskii, Stanislav K.; Matveev, Dmitrii A.

In: Journal of Organometallic Chemistry, Vol. 696, No. 22, 01.11.2011, p. 3483-3490.

Research output: Contribution to journal › Article › peer-review

Harvard

Kraikivskii, PB, Saraev, VV, Bocharova, VV, Romanenko, GV, Petrovskii, SK & Matveev, DA 2011, 'Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 - (2,6-diisopropylphenyl)diazabutadiene system', Journal of Organometallic Chemistry, vol. 696, no. 22, pp. 3483-3490. https://doi.org/10.1016/j.jorganchem.2011.07.023

APA

Kraikivskii, P. B., Saraev, V. V., Bocharova, V. V., Romanenko, G. V., Petrovskii, S. K., & Matveev, D. A. (2011). Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 - (2,6-diisopropylphenyl)diazabutadiene system. Journal of Organometallic Chemistry, 696(22), 3483-3490. https://doi.org/10.1016/j.jorganchem.2011.07.023

Vancouver

Kraikivskii PB, Saraev VV, Bocharova VV, Romanenko GV, Petrovskii SK, Matveev DA. Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 - (2,6-diisopropylphenyl)diazabutadiene system. Journal of Organometallic Chemistry. 2011 Nov 1;696(22):3483-3490. https://doi.org/10.1016/j.jorganchem.2011.07.023

Author

Kraikivskii, Peter B. ; Saraev, Vitaly V. ; Bocharova, Victoria V. ; Romanenko, Galina V. ; Petrovskii, Stanislav K. ; Matveev, Dmitrii A. / Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 - (2,6-diisopropylphenyl)diazabutadiene system. In: Journal of Organometallic Chemistry. 2011 ; Vol. 696, No. 22. pp. 3483-3490.

BibTeX

@article{db1366387f7342d7a7e6fd86f0920876,
title = "Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 - (2,6-diisopropylphenyl)diazabutadiene system",
abstract = "It has been shown that the reaction of Ni(allyl)2 with (2,6-diisopropylphenyl)diazabutadiene gives the imino-amide Ni complex (1). The imino-amide moiety of this complex undergoes some complicated rearrangements resulting in spontaneous formation of a paramagnetic π-allyl Ni(I) complex. Nickel complexes formed in the system have been studied with ESR, FTIR, 2D NMR, and mass spectrometry. The structure of complex 1 was studied with X-ray diffraction.",
keywords = "Chelates, Diimine ligands, Monovalent nickel, Structure elucidation",
author = "Kraikivskii, {Peter B.} and Saraev, {Vitaly V.} and Bocharova, {Victoria V.} and Romanenko, {Galina V.} and Petrovskii, {Stanislav K.} and Matveev, {Dmitrii A.}",
year = "2011",
month = nov,
day = "1",
doi = "10.1016/j.jorganchem.2011.07.023",
language = "English",
volume = "696",
pages = "3483--3490",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "22",

}

RIS

TY - JOUR

T1 - Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 - (2,6-diisopropylphenyl)diazabutadiene system

AU - Kraikivskii, Peter B.

AU - Saraev, Vitaly V.

AU - Bocharova, Victoria V.

AU - Romanenko, Galina V.

AU - Petrovskii, Stanislav K.

AU - Matveev, Dmitrii A.

PY - 2011/11/1

Y1 - 2011/11/1

N2 - It has been shown that the reaction of Ni(allyl)2 with (2,6-diisopropylphenyl)diazabutadiene gives the imino-amide Ni complex (1). The imino-amide moiety of this complex undergoes some complicated rearrangements resulting in spontaneous formation of a paramagnetic π-allyl Ni(I) complex. Nickel complexes formed in the system have been studied with ESR, FTIR, 2D NMR, and mass spectrometry. The structure of complex 1 was studied with X-ray diffraction.

AB - It has been shown that the reaction of Ni(allyl)2 with (2,6-diisopropylphenyl)diazabutadiene gives the imino-amide Ni complex (1). The imino-amide moiety of this complex undergoes some complicated rearrangements resulting in spontaneous formation of a paramagnetic π-allyl Ni(I) complex. Nickel complexes formed in the system have been studied with ESR, FTIR, 2D NMR, and mass spectrometry. The structure of complex 1 was studied with X-ray diffraction.

KW - Chelates

KW - Diimine ligands

KW - Monovalent nickel

KW - Structure elucidation

UR - http://www.scopus.com/inward/record.url?scp=80052964274&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2011.07.023

DO - 10.1016/j.jorganchem.2011.07.023

M3 - Article

AN - SCOPUS:80052964274

VL - 696

SP - 3483

EP - 3490

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 22

ER -

ID: 51891492