Research output: Contribution to journal › Article › peer-review
It has been shown that the reaction of Ni(allyl)2 with (2,6-diisopropylphenyl)diazabutadiene gives the imino-amide Ni complex (1). The imino-amide moiety of this complex undergoes some complicated rearrangements resulting in spontaneous formation of a paramagnetic π-allyl Ni(I) complex. Nickel complexes formed in the system have been studied with ESR, FTIR, 2D NMR, and mass spectrometry. The structure of complex 1 was studied with X-ray diffraction.
Original language | English |
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Pages (from-to) | 3483-3490 |
Number of pages | 8 |
Journal | Journal of Organometallic Chemistry |
Volume | 696 |
Issue number | 22 |
DOIs | |
State | Published - 1 Nov 2011 |
ID: 51891492