Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 - (2,6-diisopropylphenyl)diazabutadiene system. / Kraikivskii, Peter B.; Saraev, Vitaly V.; Bocharova, Victoria V.; Romanenko, Galina V.; Petrovskii, Stanislav K.; Matveev, Dmitrii A.
в: Journal of Organometallic Chemistry, Том 696, № 22, 01.11.2011, стр. 3483-3490.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Formation of the paramagletic Ni(I) π-allyl complex in the Ni(allyl)2 - (2,6-diisopropylphenyl)diazabutadiene system
AU - Kraikivskii, Peter B.
AU - Saraev, Vitaly V.
AU - Bocharova, Victoria V.
AU - Romanenko, Galina V.
AU - Petrovskii, Stanislav K.
AU - Matveev, Dmitrii A.
PY - 2011/11/1
Y1 - 2011/11/1
N2 - It has been shown that the reaction of Ni(allyl)2 with (2,6-diisopropylphenyl)diazabutadiene gives the imino-amide Ni complex (1). The imino-amide moiety of this complex undergoes some complicated rearrangements resulting in spontaneous formation of a paramagnetic π-allyl Ni(I) complex. Nickel complexes formed in the system have been studied with ESR, FTIR, 2D NMR, and mass spectrometry. The structure of complex 1 was studied with X-ray diffraction.
AB - It has been shown that the reaction of Ni(allyl)2 with (2,6-diisopropylphenyl)diazabutadiene gives the imino-amide Ni complex (1). The imino-amide moiety of this complex undergoes some complicated rearrangements resulting in spontaneous formation of a paramagnetic π-allyl Ni(I) complex. Nickel complexes formed in the system have been studied with ESR, FTIR, 2D NMR, and mass spectrometry. The structure of complex 1 was studied with X-ray diffraction.
KW - Chelates
KW - Diimine ligands
KW - Monovalent nickel
KW - Structure elucidation
UR - http://www.scopus.com/inward/record.url?scp=80052964274&partnerID=8YFLogxK
U2 - 10.1016/j.jorganchem.2011.07.023
DO - 10.1016/j.jorganchem.2011.07.023
M3 - Article
AN - SCOPUS:80052964274
VL - 696
SP - 3483
EP - 3490
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 22
ER -
ID: 51891492