The main purpose of the article is to present and discuss the results of the study of network approach possibilities in the comparative analysis of the values of entrepreneurship, both from the content and from the methodological sides. It is shown that the values can serve as a universal object of comparative research of entrepreneur groups. In particular, the network analysis of values allows us to compare the activities of Russian and Chinese entrepreneurs and to identify their important characteristics. Basing on the network diagnostics of Russian and Chinese entrepreneurs’ values, the authors identify and form networks of values of Russian and Chinese entrepreneurs, establish matrices for comparison of terminal values of Russian and Chinese entrepreneurs, and present an approach for comparative analysis of values of Chinese entrepreneurs in the system of values of Russians. The authors make conclusions about the features of the values of entrepreneurship of Russians and the Chinese.