Результаты исследований: Научные публикации в периодических изданиях › статья
Vibrational Spectra of Monoisotopic SiH4 and GeH4 in Low-Temperature Matrices. / Kolomiitsova, T.D.; Savvateev, K. F.; Shchepkin, D. N.; Tokhadze, К.G.; Bulanov, A. D.; Sennikov, P. G.; A.Vel’muzhova, I.
в: Optics and Spectroscopy (English translation of Optika i Spektroskopiya), Том 112, № 4, 2012, стр. 563–573.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Vibrational Spectra of Monoisotopic SiH4 and GeH4 in Low-Temperature Matrices
AU - Kolomiitsova, T.D.
AU - Savvateev, K. F.
AU - Shchepkin, D. N.
AU - Tokhadze, К.G.
AU - Bulanov, A. D.
AU - Sennikov, P. G.
AU - A.Vel’muzhova, I.
PY - 2012
Y1 - 2012
N2 - IR absorption spectra of monoisotopic 28SiH4 and 76GeH4 are studied in Ar and N2 matrices at 10 K. It is shown that the absorption spectra of silane and germane are similar in the regions of the stretching ν3 and bending ν4 vibrations. Four groups of bands can be separated out in the spectra of each molecule: (1) narrow bands characteristic of the matrix isolation studies, (2) broad bands, (3) diffuse absorption with alarge value of the spectral moment the intensity of which increases upon annealing, and (4) bands ofdimers the intensity of which increases quadratically with concentration. The spectra of 28SiH4 and 76GeH4 in nitrogen matrices contain a triplet in the stretching region and a doublet in the bending region, which isexplained by the change in the molecular symmetry from Td to C3V on passage from the gas phase to solid nitrogen.
AB - IR absorption spectra of monoisotopic 28SiH4 and 76GeH4 are studied in Ar and N2 matrices at 10 K. It is shown that the absorption spectra of silane and germane are similar in the regions of the stretching ν3 and bending ν4 vibrations. Four groups of bands can be separated out in the spectra of each molecule: (1) narrow bands characteristic of the matrix isolation studies, (2) broad bands, (3) diffuse absorption with alarge value of the spectral moment the intensity of which increases upon annealing, and (4) bands ofdimers the intensity of which increases quadratically with concentration. The spectra of 28SiH4 and 76GeH4 in nitrogen matrices contain a triplet in the stretching region and a doublet in the bending region, which isexplained by the change in the molecular symmetry from Td to C3V on passage from the gas phase to solid nitrogen.
U2 - DOI: 10.1134/S0030400X12030113
DO - DOI: 10.1134/S0030400X12030113
M3 - Article
VL - 112
SP - 563
EP - 573
JO - OPTICS AND SPECTROSCOPY
JF - OPTICS AND SPECTROSCOPY
SN - 0030-400X
IS - 4
ER -
ID: 5488471