DOI

The emission of the radiative dissociation continuum of the hydrogen molecule [Formula Presented] electronic transition) is proposed to be used as a source of information for the spectroscopic diagnostics of nonequilibrium plasmas. The detailed analysis of excitation-deactivation kinetics, rate constants of various collisional and radiative transitions, and fitting procedures made it possible to develop two methods of diagnostics of (1) the ground [Formula Presented] state vibrational temperature [Formula Presented] from the relative intensity distribution, and (2) the rate of electron impact dissociation [Formula Presented] from the absolute intensity of the continuum. The known method of determination of [Formula Presented] from relative intensities of Fulcher-[Formula Presented] bands was corrected and simplified due to the revision of [Formula Presented] transition probabilities and cross sections of [Formula Presented] electron impact excitation. General considerations are illustrated with examples of experiments in pure hydrogen capillary-arc and [Formula Presented] microwave discharges. In pure [Formula Presented] plasma the values of [Formula Presented] obtained by two independent methods are in rather good accordance [Formula Presented] In the [Formula Presented] microwave plasma it was observed that the shape of the continuum depends on the ratio of the mixture components. Absorption measurements of the population of the [Formula Presented] levels of Ar together with certain computer simulations showed that the [Formula Presented] excitation transfer plays a significant role. In our typical conditions (power flux: [Formula Presented] pressure [Formula Presented] the following values were obtained for the microwave discharge: [Formula Presented] The contribution of the excitation transfer is about 10–30 % of the total population of the [Formula Presented] state.

Язык оригиналаанглийский
Страницы (с-по)3526-3543
Число страниц18
ЖурналPhysical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
Том59
Номер выпуска3
DOI
СостояниеОпубликовано - 1 янв 1999

    Предметные области Scopus

  • Статистическая и нелинейная физика
  • Математическая физика
  • Физика конденсатов
  • Физика и астрономия (все)

ID: 36195323