DOI

The emission of the radiative dissociation continuum of the hydrogen molecule [Formula Presented] electronic transition) is proposed to be used as a source of information for the spectroscopic diagnostics of nonequilibrium plasmas. The detailed analysis of excitation-deactivation kinetics, rate constants of various collisional and radiative transitions, and fitting procedures made it possible to develop two methods of diagnostics of (1) the ground [Formula Presented] state vibrational temperature [Formula Presented] from the relative intensity distribution, and (2) the rate of electron impact dissociation [Formula Presented] from the absolute intensity of the continuum. The known method of determination of [Formula Presented] from relative intensities of Fulcher-[Formula Presented] bands was corrected and simplified due to the revision of [Formula Presented] transition probabilities and cross sections of [Formula Presented] electron impact excitation. General considerations are illustrated with examples of experiments in pure hydrogen capillary-arc and [Formula Presented] microwave discharges. In pure [Formula Presented] plasma the values of [Formula Presented] obtained by two independent methods are in rather good accordance [Formula Presented] In the [Formula Presented] microwave plasma it was observed that the shape of the continuum depends on the ratio of the mixture components. Absorption measurements of the population of the [Formula Presented] levels of Ar together with certain computer simulations showed that the [Formula Presented] excitation transfer plays a significant role. In our typical conditions (power flux: [Formula Presented] pressure [Formula Presented] the following values were obtained for the microwave discharge: [Formula Presented] The contribution of the excitation transfer is about 10–30 % of the total population of the [Formula Presented] state.

Original languageEnglish
Pages (from-to)3526-3543
Number of pages18
JournalPhysical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
Volume59
Issue number3
DOIs
StatePublished - 1 Jan 1999

    Scopus subject areas

  • Statistical and Nonlinear Physics
  • Mathematical Physics
  • Condensed Matter Physics
  • Physics and Astronomy(all)

ID: 36195323