Standard

Unusual iodination of arylsulfonylallenes. / Lozovskiy, Stanislav V.; Vasilyev, Aleksander V.

в: Mendeleev Communications , Том 29, № 1, 01.01.2019, стр. 19-21.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

APA

Vancouver

Author

Lozovskiy, Stanislav V. ; Vasilyev, Aleksander V. / Unusual iodination of arylsulfonylallenes. в: Mendeleev Communications . 2019 ; Том 29, № 1. стр. 19-21.

BibTeX

@article{5cbb8bc2af9747a08250abcddb0276cb,
title = "Unusual iodination of arylsulfonylallenes",
abstract = " Arysulfonylallenes (ArSO 2 –CR 1 =C=CR 2 R 3 ), depending on their structure, react with iodine to give two types of products, diiodo alkenes ArSO 2 –CHI–CI=CR 2 R 3 , when R 1 = H, or iodo dienes ArSO 2 –CR 1 =CI–C(Me)=CH 2 , when R 1 = Br, Ph and R 2 = R 3 = Me, in yields of 55–98%. The plausible reaction mechanisms have been proposed. ",
keywords = "ALLENES",
author = "Lozovskiy, {Stanislav V.} and Vasilyev, {Aleksander V.}",
year = "2019",
month = jan,
day = "1",
doi = "10.1016/j.mencom.2019.01.005",
language = "English",
volume = "29",
pages = "19--21",
journal = "Mendeleev Communications",
issn = "0959-9436",
publisher = "Elsevier",
number = "1",

}

RIS

TY - JOUR

T1 - Unusual iodination of arylsulfonylallenes

AU - Lozovskiy, Stanislav V.

AU - Vasilyev, Aleksander V.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - Arysulfonylallenes (ArSO 2 –CR 1 =C=CR 2 R 3 ), depending on their structure, react with iodine to give two types of products, diiodo alkenes ArSO 2 –CHI–CI=CR 2 R 3 , when R 1 = H, or iodo dienes ArSO 2 –CR 1 =CI–C(Me)=CH 2 , when R 1 = Br, Ph and R 2 = R 3 = Me, in yields of 55–98%. The plausible reaction mechanisms have been proposed.

AB - Arysulfonylallenes (ArSO 2 –CR 1 =C=CR 2 R 3 ), depending on their structure, react with iodine to give two types of products, diiodo alkenes ArSO 2 –CHI–CI=CR 2 R 3 , when R 1 = H, or iodo dienes ArSO 2 –CR 1 =CI–C(Me)=CH 2 , when R 1 = Br, Ph and R 2 = R 3 = Me, in yields of 55–98%. The plausible reaction mechanisms have been proposed.

KW - ALLENES

UR - http://www.scopus.com/inward/record.url?scp=85061550551&partnerID=8YFLogxK

U2 - 10.1016/j.mencom.2019.01.005

DO - 10.1016/j.mencom.2019.01.005

M3 - Article

AN - SCOPUS:85061550551

VL - 29

SP - 19

EP - 21

JO - Mendeleev Communications

JF - Mendeleev Communications

SN - 0959-9436

IS - 1

ER -

ID: 44001544