Research output: Contribution to journal › Article › peer-review
Unusual iodination of arylsulfonylallenes. / Lozovskiy, Stanislav V.; Vasilyev, Aleksander V.
In: Mendeleev Communications , Vol. 29, No. 1, 01.01.2019, p. 19-21.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Unusual iodination of arylsulfonylallenes
AU - Lozovskiy, Stanislav V.
AU - Vasilyev, Aleksander V.
PY - 2019/1/1
Y1 - 2019/1/1
N2 - Arysulfonylallenes (ArSO 2 –CR 1 =C=CR 2 R 3 ), depending on their structure, react with iodine to give two types of products, diiodo alkenes ArSO 2 –CHI–CI=CR 2 R 3 , when R 1 = H, or iodo dienes ArSO 2 –CR 1 =CI–C(Me)=CH 2 , when R 1 = Br, Ph and R 2 = R 3 = Me, in yields of 55–98%. The plausible reaction mechanisms have been proposed.
AB - Arysulfonylallenes (ArSO 2 –CR 1 =C=CR 2 R 3 ), depending on their structure, react with iodine to give two types of products, diiodo alkenes ArSO 2 –CHI–CI=CR 2 R 3 , when R 1 = H, or iodo dienes ArSO 2 –CR 1 =CI–C(Me)=CH 2 , when R 1 = Br, Ph and R 2 = R 3 = Me, in yields of 55–98%. The plausible reaction mechanisms have been proposed.
KW - ALLENES
UR - http://www.scopus.com/inward/record.url?scp=85061550551&partnerID=8YFLogxK
U2 - 10.1016/j.mencom.2019.01.005
DO - 10.1016/j.mencom.2019.01.005
M3 - Article
AN - SCOPUS:85061550551
VL - 29
SP - 19
EP - 21
JO - Mendeleev Communications
JF - Mendeleev Communications
SN - 0959-9436
IS - 1
ER -
ID: 44001544