Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties. / Usoltsev, Andrey N.; Sukhikh, Taisiya S.; Novikov, Alexander S.; Shayapov, Vladimir R.; Pishchur, Denis P.; Korolkov, Ilya V.; Sakhapov, Ilyas F.; Fedin, Vladimir P.; Sokolov, Maxim N.; Adonin, Sergey A.
в: Inorganic Chemistry, Том 60, № 4, 26.01.2021, стр. 2797-2804.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties
AU - Usoltsev, Andrey N.
AU - Sukhikh, Taisiya S.
AU - Novikov, Alexander S.
AU - Shayapov, Vladimir R.
AU - Pishchur, Denis P.
AU - Korolkov, Ilya V.
AU - Sakhapov, Ilyas F.
AU - Fedin, Vladimir P.
AU - Sokolov, Maxim N.
AU - Adonin, Sergey A.
N1 - Publisher Copyright: © 2021 American Chemical Society. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/1/26
Y1 - 2021/1/26
N2 - Reactions of [SbBr6]3- containing HBr solutions with bromide salts of 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC22+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC22+) initially result in the formation of the deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br interactions in the solid state. In the mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 and monoclinic 4), while 2 transforms into polymeric (3,5-MePy){[SbBr4]} (5). DFT calculations reveal that the system of noncovalent Sb···Br contacts may be responsible for the appearance of the observed optical properties (unusual deep orange coloring).
AB - Reactions of [SbBr6]3- containing HBr solutions with bromide salts of 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC22+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC22+) initially result in the formation of the deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br interactions in the solid state. In the mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 and monoclinic 4), while 2 transforms into polymeric (3,5-MePy){[SbBr4]} (5). DFT calculations reveal that the system of noncovalent Sb···Br contacts may be responsible for the appearance of the observed optical properties (unusual deep orange coloring).
UR - http://www.scopus.com/inward/record.url?scp=85100804379&partnerID=8YFLogxK
U2 - 10.1021/acs.inorgchem.0c03699
DO - 10.1021/acs.inorgchem.0c03699
M3 - Article
C2 - 33496171
AN - SCOPUS:85100804379
VL - 60
SP - 2797
EP - 2804
JO - Inorganic Chemistry
JF - Inorganic Chemistry
SN - 0020-1669
IS - 4
ER -
ID: 77246724