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Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties. / Usoltsev, Andrey N.; Sukhikh, Taisiya S.; Novikov, Alexander S.; Shayapov, Vladimir R.; Pishchur, Denis P.; Korolkov, Ilya V.; Sakhapov, Ilyas F.; Fedin, Vladimir P.; Sokolov, Maxim N.; Adonin, Sergey A.

In: Inorganic Chemistry, Vol. 60, No. 4, 26.01.2021, p. 2797-2804.

Research output: Contribution to journal › Article › peer-review

Harvard

Usoltsev, AN, Sukhikh, TS, Novikov, AS, Shayapov, VR, Pishchur, DP, Korolkov, IV, Sakhapov, IF, Fedin, VP, Sokolov, MN & Adonin, SA 2021, 'Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties', Inorganic Chemistry, vol. 60, no. 4, pp. 2797-2804. https://doi.org/10.1021/acs.inorgchem.0c03699

APA

Usoltsev, A. N., Sukhikh, T. S., Novikov, A. S., Shayapov, V. R., Pishchur, D. P., Korolkov, I. V., Sakhapov, I. F., Fedin, V. P., Sokolov, M. N., & Adonin, S. A. (2021). Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties. Inorganic Chemistry, 60(4), 2797-2804. https://doi.org/10.1021/acs.inorgchem.0c03699

Vancouver

Usoltsev AN, Sukhikh TS, Novikov AS, Shayapov VR, Pishchur DP, Korolkov IV et al. Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties. Inorganic Chemistry. 2021 Jan 26;60(4):2797-2804. https://doi.org/10.1021/acs.inorgchem.0c03699

Author

Usoltsev, Andrey N. ; Sukhikh, Taisiya S. ; Novikov, Alexander S. ; Shayapov, Vladimir R. ; Pishchur, Denis P. ; Korolkov, Ilya V. ; Sakhapov, Ilyas F. ; Fedin, Vladimir P. ; Sokolov, Maxim N. ; Adonin, Sergey A. / Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties. In: Inorganic Chemistry. 2021 ; Vol. 60, No. 4. pp. 2797-2804.

BibTeX

@article{47b3e93cdfb04cceafd11832f14b859f,
title = "Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties",
abstract = "Reactions of [SbBr6]3- containing HBr solutions with bromide salts of 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC22+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC22+) initially result in the formation of the deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br interactions in the solid state. In the mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 and monoclinic 4), while 2 transforms into polymeric (3,5-MePy){[SbBr4]} (5). DFT calculations reveal that the system of noncovalent Sb···Br contacts may be responsible for the appearance of the observed optical properties (unusual deep orange coloring).",
author = "Usoltsev, {Andrey N.} and Sukhikh, {Taisiya S.} and Novikov, {Alexander S.} and Shayapov, {Vladimir R.} and Pishchur, {Denis P.} and Korolkov, {Ilya V.} and Sakhapov, {Ilyas F.} and Fedin, {Vladimir P.} and Sokolov, {Maxim N.} and Adonin, {Sergey A.}",
note = "Publisher Copyright: {\textcopyright} 2021 American Chemical Society. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.",
year = "2021",
month = jan,
day = "26",
doi = "10.1021/acs.inorgchem.0c03699",
language = "English",
volume = "60",
pages = "2797--2804",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "4",

}

RIS

TY - JOUR

T1 - Unexpected Polymorphism in Bromoantimonate(III) Complexes and Its Effect on Optical Properties

AU - Usoltsev, Andrey N.

AU - Sukhikh, Taisiya S.

AU - Novikov, Alexander S.

AU - Shayapov, Vladimir R.

AU - Pishchur, Denis P.

AU - Korolkov, Ilya V.

AU - Sakhapov, Ilyas F.

AU - Fedin, Vladimir P.

AU - Sokolov, Maxim N.

AU - Adonin, Sergey A.

N1 - Publisher Copyright: © 2021 American Chemical Society. Copyright: Copyright 2021 Elsevier B.V., All rights reserved.

PY - 2021/1/26

Y1 - 2021/1/26

N2 - Reactions of [SbBr6]3- containing HBr solutions with bromide salts of 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC22+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC22+) initially result in the formation of the deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br interactions in the solid state. In the mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 and monoclinic 4), while 2 transforms into polymeric (3,5-MePy){[SbBr4]} (5). DFT calculations reveal that the system of noncovalent Sb···Br contacts may be responsible for the appearance of the observed optical properties (unusual deep orange coloring).

AB - Reactions of [SbBr6]3- containing HBr solutions with bromide salts of 1,1′-(1,2-ethanediyl)bis(pyridine) (PyC22+) or 1,1′-(1,2-ethanediyl)bis(3,5-dimethylpyridine) (3,5-MePyC22+) initially result in the formation of the deep orange complexes Cat[SbBr5] (1 and 2), featuring unusual Sb···Br interactions in the solid state. In the mother liquor, 1 transforms into discrete binuclear (C2Py)2[Sb2Br10], which demonstrates polymorphism (triclinic 3 and monoclinic 4), while 2 transforms into polymeric (3,5-MePy){[SbBr4]} (5). DFT calculations reveal that the system of noncovalent Sb···Br contacts may be responsible for the appearance of the observed optical properties (unusual deep orange coloring).

UR - http://www.scopus.com/inward/record.url?scp=85100804379&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.0c03699

DO - 10.1021/acs.inorgchem.0c03699

M3 - Article

C2 - 33496171

AN - SCOPUS:85100804379

VL - 60

SP - 2797

EP - 2804

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 4

ER -

ID: 77246724