Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Time-resolved inner-shell photoelectron spectroscopy : From a bound molecule to an isolated atom. / Brasse, Felix; Goldsztejn, Gildas; Amini, Kasra; Boll, Rebecca; Bari, Sadia; Bomme, Cedric; Brouard, Mark; Burt, Michael; de Miranda, Barbara Cunha; Duesterer, Stefan; Erk, Benjamin; Geleoc, Marie; Geneaux, Romain; Gentleman, Alexander S.; Guillemin, Renaud; Ismail, Iyas; Johnsson, Per; Journel, Loic; Kierspel, Thomas; Kockert, Hansjochen; Kuepper, Jochen; Lablanquie, Pascal; Lahl, Jan; Lee, Jason W. L.; Mackenzie, Stuart R.; Maclot, Sylvain; Manschwetus, Bastian; Mereshchenko, Andrey S.; Mullins, Terence; Olshin, Pavel K.; Palaudoux, Jerome; Patchkovskii, Serguei; Penent, Francis; Piancastelli, Maria Novella; Rompotis, Dimitrios; Ruchon, Thierry; Rudenko, Artem; Savelyev, Evgeny; Schirmel, Nora; Techert, Simone; Travnikova, Oksana; Trippel, Sebastian; Underwood, Jonathan G.; Vallance, Claire; Wiese, Joss; Simon, Marc; Holland, David M. P.; Marchenko, Tatiana; Rouzee, Arnaud; Rolles, Daniel.
в: Physical Review A - Atomic, Molecular, and Optical Physics, Том 97, № 4, 043429, 27.04.2018.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Time-resolved inner-shell photoelectron spectroscopy
T2 - From a bound molecule to an isolated atom
AU - Brasse, Felix
AU - Goldsztejn, Gildas
AU - Amini, Kasra
AU - Boll, Rebecca
AU - Bari, Sadia
AU - Bomme, Cedric
AU - Brouard, Mark
AU - Burt, Michael
AU - de Miranda, Barbara Cunha
AU - Duesterer, Stefan
AU - Erk, Benjamin
AU - Geleoc, Marie
AU - Geneaux, Romain
AU - Gentleman, Alexander S.
AU - Guillemin, Renaud
AU - Ismail, Iyas
AU - Johnsson, Per
AU - Journel, Loic
AU - Kierspel, Thomas
AU - Kockert, Hansjochen
AU - Kuepper, Jochen
AU - Lablanquie, Pascal
AU - Lahl, Jan
AU - Lee, Jason W. L.
AU - Mackenzie, Stuart R.
AU - Maclot, Sylvain
AU - Manschwetus, Bastian
AU - Mereshchenko, Andrey S.
AU - Mullins, Terence
AU - Olshin, Pavel K.
AU - Palaudoux, Jerome
AU - Patchkovskii, Serguei
AU - Penent, Francis
AU - Piancastelli, Maria Novella
AU - Rompotis, Dimitrios
AU - Ruchon, Thierry
AU - Rudenko, Artem
AU - Savelyev, Evgeny
AU - Schirmel, Nora
AU - Techert, Simone
AU - Travnikova, Oksana
AU - Trippel, Sebastian
AU - Underwood, Jonathan G.
AU - Vallance, Claire
AU - Wiese, Joss
AU - Simon, Marc
AU - Holland, David M. P.
AU - Marchenko, Tatiana
AU - Rouzee, Arnaud
AU - Rolles, Daniel
PY - 2018/4/27
Y1 - 2018/4/27
N2 - Due to its element and site specificity, inner-shell photoelectron spectroscopy is a widely used technique to probe the chemical structure of matter. Here, we show that time-resolved inner-shell photoelectron spectroscopy can be employed to observe ultrafast chemical reactions and the electronic response to the nuclear motion with high sensitivity. The ultraviolet dissociation of iodomethane (CH3I) is investigated by ionization above the iodine 4d edge, using time-resolved inner-shell photoelectron and photoion spectroscopy. The dynamics observed in the photoelectron spectra appear earlier and are faster than those seen in the iodine fragments. The experimental results are interpreted using crystal-field and spin-orbit configuration interaction calculations, and demonstrate that time-resolved inner-shell photoelectron spectroscopy is a powerful tool to directly track ultrafast structural and electronic transformations in gas-phase molecules.
AB - Due to its element and site specificity, inner-shell photoelectron spectroscopy is a widely used technique to probe the chemical structure of matter. Here, we show that time-resolved inner-shell photoelectron spectroscopy can be employed to observe ultrafast chemical reactions and the electronic response to the nuclear motion with high sensitivity. The ultraviolet dissociation of iodomethane (CH3I) is investigated by ionization above the iodine 4d edge, using time-resolved inner-shell photoelectron and photoion spectroscopy. The dynamics observed in the photoelectron spectra appear earlier and are faster than those seen in the iodine fragments. The experimental results are interpreted using crystal-field and spin-orbit configuration interaction calculations, and demonstrate that time-resolved inner-shell photoelectron spectroscopy is a powerful tool to directly track ultrafast structural and electronic transformations in gas-phase molecules.
KW - FREE-ELECTRON LASER
KW - CONICAL INTERSECTIONS
KW - SYNCHROTRON-RADIATION
KW - METHYL-IODIDE
KW - DYNAMICS
KW - PHOTODISSOCIATION
KW - PHOTOIONIZATION
KW - PHOTOABSORPTION
KW - ENERGY
KW - FIELD
UR - http://www.mendeley.com/research/timeresolved-innershell-photoelectron-spectroscopy-bound-molecule-isolated-atom
U2 - 10.1103/PhysRevA.97.043429
DO - 10.1103/PhysRevA.97.043429
M3 - статья
VL - 97
JO - Physical Review A - Atomic, Molecular, and Optical Physics
JF - Physical Review A - Atomic, Molecular, and Optical Physics
SN - 1050-2947
IS - 4
M1 - 043429
ER -
ID: 27324932