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Time resolved studies of decay of the XeI2(IP) complexes. / Akopyan, M. E.; Lukashov, S. S.; Maslennikova, Yu D.; Poretsky, S. A.; Pravilov, A. M.
в: Chemical Physics, Том 362, № 1-2, 30.07.2009, стр. 27-33.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Time resolved studies of decay of the XeI2(IP) complexes
AU - Akopyan, M. E.
AU - Lukashov, S. S.
AU - Maslennikova, Yu D.
AU - Poretsky, S. A.
AU - Pravilov, A. M.
N1 - Copyright: Copyright 2009 Elsevier B.V., All rights reserved.
PY - 2009/7/30
Y1 - 2009/7/30
N2 - Results of the first studies of temporal behavior of luminescence in the λ = 235-275 nm and λ = 315-350 nm spectral ranges following optical-optical double resonance (OODR) excitation of I2 + Xe mixtures to the I2(f, vf = 9, Jf ≈ 55) state as well as time-gated luminescence spectra measured with Δt = 10-70 ns time delay from the beginning of the laser probe pulse, I2 (f, vf, Jf over(←, hvp) B, vB, JB) have been described. The spectra look as quasi-continua superimposed with transition bands from the optically and collisionally populated I2(f, vf = 9, Jf ≈ 55) and I2(F, vF = 1-11) states. The temporal histories of luminescence at the bands and quasi-continua differ significantly. It is shown that, to describe the quasi-continuum in the λ = 315-350 nm time-gated experimental spectra, transitions other than the I2(f, vf → B, vB) one have to be used. The I2(f and F) vibrational state distributions observed in experiments can be formed as result of predissociation of long-life XeI2(IP) complexes. The quasi-continuum in the λ ≈ 330-350 nm spectral ranges can belong to the XeI2(f → B) transition.
AB - Results of the first studies of temporal behavior of luminescence in the λ = 235-275 nm and λ = 315-350 nm spectral ranges following optical-optical double resonance (OODR) excitation of I2 + Xe mixtures to the I2(f, vf = 9, Jf ≈ 55) state as well as time-gated luminescence spectra measured with Δt = 10-70 ns time delay from the beginning of the laser probe pulse, I2 (f, vf, Jf over(←, hvp) B, vB, JB) have been described. The spectra look as quasi-continua superimposed with transition bands from the optically and collisionally populated I2(f, vf = 9, Jf ≈ 55) and I2(F, vF = 1-11) states. The temporal histories of luminescence at the bands and quasi-continua differ significantly. It is shown that, to describe the quasi-continuum in the λ = 315-350 nm time-gated experimental spectra, transitions other than the I2(f, vf → B, vB) one have to be used. The I2(f and F) vibrational state distributions observed in experiments can be formed as result of predissociation of long-life XeI2(IP) complexes. The quasi-continuum in the λ ≈ 330-350 nm spectral ranges can belong to the XeI2(f → B) transition.
KW - Ion-pair states
KW - Non-adiabatic transitions
KW - Optical population
KW - Van der Waals complexes
UR - http://www.scopus.com/inward/record.url?scp=67650601412&partnerID=8YFLogxK
U2 - 10.1016/j.chemphys.2009.06.003
DO - 10.1016/j.chemphys.2009.06.003
M3 - Article
AN - SCOPUS:67650601412
VL - 362
SP - 27
EP - 33
JO - Chemical Physics
JF - Chemical Physics
SN - 0301-0104
IS - 1-2
ER -
ID: 77095983