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Time resolved studies of decay of the XeI2(IP) complexes. / Akopyan, M. E.; Lukashov, S. S.; Maslennikova, Yu D.; Poretsky, S. A.; Pravilov, A. M.

In: Chemical Physics, Vol. 362, No. 1-2, 30.07.2009, p. 27-33.

Research output: Contribution to journal › Article › peer-review

Harvard

Akopyan, ME, Lukashov, SS, Maslennikova, YD, Poretsky, SA & Pravilov, AM 2009, 'Time resolved studies of decay of the XeI2(IP) complexes', Chemical Physics, vol. 362, no. 1-2, pp. 27-33. https://doi.org/10.1016/j.chemphys.2009.06.003

APA

Akopyan, M. E., Lukashov, S. S., Maslennikova, Y. D., Poretsky, S. A., & Pravilov, A. M. (2009). Time resolved studies of decay of the XeI2(IP) complexes. Chemical Physics, 362(1-2), 27-33. https://doi.org/10.1016/j.chemphys.2009.06.003

Vancouver

Akopyan ME, Lukashov SS, Maslennikova YD, Poretsky SA, Pravilov AM. Time resolved studies of decay of the XeI2(IP) complexes. Chemical Physics. 2009 Jul 30;362(1-2):27-33. https://doi.org/10.1016/j.chemphys.2009.06.003

Author

Akopyan, M. E. ; Lukashov, S. S. ; Maslennikova, Yu D. ; Poretsky, S. A. ; Pravilov, A. M. / Time resolved studies of decay of the XeI2(IP) complexes. In: Chemical Physics. 2009 ; Vol. 362, No. 1-2. pp. 27-33.

BibTeX

@article{e832ff10a9844626a21a71d120b18889,
title = "Time resolved studies of decay of the XeI2(IP) complexes",
abstract = "Results of the first studies of temporal behavior of luminescence in the λ = 235-275 nm and λ = 315-350 nm spectral ranges following optical-optical double resonance (OODR) excitation of I2 + Xe mixtures to the I2(f, vf = 9, Jf ≈ 55) state as well as time-gated luminescence spectra measured with Δt = 10-70 ns time delay from the beginning of the laser probe pulse, I2 (f, vf, Jf over(←, hvp) B, vB, JB) have been described. The spectra look as quasi-continua superimposed with transition bands from the optically and collisionally populated I2(f, vf = 9, Jf ≈ 55) and I2(F, vF = 1-11) states. The temporal histories of luminescence at the bands and quasi-continua differ significantly. It is shown that, to describe the quasi-continuum in the λ = 315-350 nm time-gated experimental spectra, transitions other than the I2(f, vf → B, vB) one have to be used. The I2(f and F) vibrational state distributions observed in experiments can be formed as result of predissociation of long-life XeI2(IP) complexes. The quasi-continuum in the λ ≈ 330-350 nm spectral ranges can belong to the XeI2(f → B) transition.",
keywords = "Ion-pair states, Non-adiabatic transitions, Optical population, Van der Waals complexes",
author = "Akopyan, {M. E.} and Lukashov, {S. S.} and Maslennikova, {Yu D.} and Poretsky, {S. A.} and Pravilov, {A. M.}",
note = "Copyright: Copyright 2009 Elsevier B.V., All rights reserved.",
year = "2009",
month = jul,
day = "30",
doi = "10.1016/j.chemphys.2009.06.003",
language = "English",
volume = "362",
pages = "27--33",
journal = "Chemical Physics",
issn = "0301-0104",
publisher = "Elsevier",
number = "1-2",

}

RIS

TY - JOUR

T1 - Time resolved studies of decay of the XeI2(IP) complexes

AU - Akopyan, M. E.

AU - Lukashov, S. S.

AU - Maslennikova, Yu D.

AU - Poretsky, S. A.

AU - Pravilov, A. M.

N1 - Copyright: Copyright 2009 Elsevier B.V., All rights reserved.

PY - 2009/7/30

Y1 - 2009/7/30

N2 - Results of the first studies of temporal behavior of luminescence in the λ = 235-275 nm and λ = 315-350 nm spectral ranges following optical-optical double resonance (OODR) excitation of I2 + Xe mixtures to the I2(f, vf = 9, Jf ≈ 55) state as well as time-gated luminescence spectra measured with Δt = 10-70 ns time delay from the beginning of the laser probe pulse, I2 (f, vf, Jf over(←, hvp) B, vB, JB) have been described. The spectra look as quasi-continua superimposed with transition bands from the optically and collisionally populated I2(f, vf = 9, Jf ≈ 55) and I2(F, vF = 1-11) states. The temporal histories of luminescence at the bands and quasi-continua differ significantly. It is shown that, to describe the quasi-continuum in the λ = 315-350 nm time-gated experimental spectra, transitions other than the I2(f, vf → B, vB) one have to be used. The I2(f and F) vibrational state distributions observed in experiments can be formed as result of predissociation of long-life XeI2(IP) complexes. The quasi-continuum in the λ ≈ 330-350 nm spectral ranges can belong to the XeI2(f → B) transition.

AB - Results of the first studies of temporal behavior of luminescence in the λ = 235-275 nm and λ = 315-350 nm spectral ranges following optical-optical double resonance (OODR) excitation of I2 + Xe mixtures to the I2(f, vf = 9, Jf ≈ 55) state as well as time-gated luminescence spectra measured with Δt = 10-70 ns time delay from the beginning of the laser probe pulse, I2 (f, vf, Jf over(←, hvp) B, vB, JB) have been described. The spectra look as quasi-continua superimposed with transition bands from the optically and collisionally populated I2(f, vf = 9, Jf ≈ 55) and I2(F, vF = 1-11) states. The temporal histories of luminescence at the bands and quasi-continua differ significantly. It is shown that, to describe the quasi-continuum in the λ = 315-350 nm time-gated experimental spectra, transitions other than the I2(f, vf → B, vB) one have to be used. The I2(f and F) vibrational state distributions observed in experiments can be formed as result of predissociation of long-life XeI2(IP) complexes. The quasi-continuum in the λ ≈ 330-350 nm spectral ranges can belong to the XeI2(f → B) transition.

KW - Ion-pair states

KW - Non-adiabatic transitions

KW - Optical population

KW - Van der Waals complexes

UR - http://www.scopus.com/inward/record.url?scp=67650601412&partnerID=8YFLogxK

U2 - 10.1016/j.chemphys.2009.06.003

DO - 10.1016/j.chemphys.2009.06.003

M3 - Article

AN - SCOPUS:67650601412

VL - 362

SP - 27

EP - 33

JO - Chemical Physics

JF - Chemical Physics

SN - 0301-0104

IS - 1-2

ER -

ID: 77095983