Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thin and Flexible Ion Sensors Based on Polyelectrolyte Multilayers Assembled onto the Carbon Adhesive Tape. / Stekolshchikova, A.A.; Radaev, A.V.; Orlova, O.Y.; Nikolaev, K.G.; Skorb, E.V.
в: ACS Omega, Том 4, № 13, 24.09.2019, стр. 15421-15427.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Thin and Flexible Ion Sensors Based on Polyelectrolyte Multilayers Assembled onto the Carbon Adhesive Tape
AU - Stekolshchikova, A.A.
AU - Radaev, A.V.
AU - Orlova, O.Y.
AU - Nikolaev, K.G.
AU - Skorb, E.V.
N1 - Publisher Copyright: © 2019 American Chemical Society.
PY - 2019/9/24
Y1 - 2019/9/24
N2 - A novel flexible ion-selective sensor for potassium and sodium detection was proposed. Flexible ion-selective electrodes with pseudo-liquid internal solution on contrary to the system with a solid contact provided a more stable analytical signal. Such advantages were achieved because of polyelectrolyte (PEI/PSS) layers adsorption on the conduct substrate with a layer-by-layer technique. Such an approach demonstrated that ion-selective electrodes save sensitivity with Nernstian dependence: 56.2 ± 1.4 mV/dec a Na + and 56.3 ± 1.9 mV/dec a K + , as well as a fast time of response for potassium (5 s) and sodium (8 s) was shown. The sensing platform proposed demonstrates a better time of response and is close to the Nernstian value of sensitivity with a sensor low cost. The results proposed confirm a pseudo-liquid junction for the ion-selective electrode. Biocompatibility of an ion-selective sensing platform was demonstrated at potassium potentiometric measurements in Escherichia coli biofilms. Potassium levels in a biofilm were measured with potentiometry and showed agreement with the previous results.
AB - A novel flexible ion-selective sensor for potassium and sodium detection was proposed. Flexible ion-selective electrodes with pseudo-liquid internal solution on contrary to the system with a solid contact provided a more stable analytical signal. Such advantages were achieved because of polyelectrolyte (PEI/PSS) layers adsorption on the conduct substrate with a layer-by-layer technique. Such an approach demonstrated that ion-selective electrodes save sensitivity with Nernstian dependence: 56.2 ± 1.4 mV/dec a Na + and 56.3 ± 1.9 mV/dec a K + , as well as a fast time of response for potassium (5 s) and sodium (8 s) was shown. The sensing platform proposed demonstrates a better time of response and is close to the Nernstian value of sensitivity with a sensor low cost. The results proposed confirm a pseudo-liquid junction for the ion-selective electrode. Biocompatibility of an ion-selective sensing platform was demonstrated at potassium potentiometric measurements in Escherichia coli biofilms. Potassium levels in a biofilm were measured with potentiometry and showed agreement with the previous results.
KW - LAYER
KW - POTASSIUM
KW - PH
UR - http://www.scopus.com/inward/record.url?scp=85072898287&partnerID=8YFLogxK
UR - http://www.mendeley.com/research/thin-flexible-ion-sensors-based-polyelectrolyte-multilayers-assembled-onto-carbon-adhesive-tape
U2 - 10.1021/acsomega.9b01464
DO - 10.1021/acsomega.9b01464
M3 - Article
C2 - 31572842
VL - 4
SP - 15421
EP - 15427
JO - ACS Omega
JF - ACS Omega
SN - 2470-1343
IS - 13
ER -
ID: 47515527