TY - JOUR

T1 - Thermodynamic fundamentals of mechanochemistry

AU - Rusanov, A. I.

PY - 2000

Y1 - 2000

N2 - The definitions of the affinity tensor and the tensor of chemical potential of an immobile component of a solid are given. The mechanochemistry of a liquid is formulated. Mechanically anisotropic states of a solid and their influence on affinity are analyzed. Thermodynamic equations are deduced relating the chemical potential tensor to the stress and strain tensors. The mechanochemistry of an ideally elastic solid and of a solid with mobile components, as well as the mechanochemistry of an interface, are formulated. As an example, the mechanochemical effect of dissolution (evaporation) is considered including its dependence on the deformation sign.

AB - The definitions of the affinity tensor and the tensor of chemical potential of an immobile component of a solid are given. The mechanochemistry of a liquid is formulated. Mechanically anisotropic states of a solid and their influence on affinity are analyzed. Thermodynamic equations are deduced relating the chemical potential tensor to the stress and strain tensors. The mechanochemistry of an ideally elastic solid and of a solid with mobile components, as well as the mechanochemistry of an interface, are formulated. As an example, the mechanochemical effect of dissolution (evaporation) is considered including its dependence on the deformation sign.

UR - http://www.scopus.com/inward/record.url?scp=0034378221&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0034378221

VL - 70

SP - 329

EP - 356

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 3

ER -