Research output: Contribution to journal › Article › peer-review
Thermodynamic fundamentals of mechanochemistry. / Rusanov, A. I.
In: Russian Journal of General Chemistry, Vol. 70, No. 3, 2000, p. 329-356.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Thermodynamic fundamentals of mechanochemistry
AU - Rusanov, A. I.
PY - 2000
Y1 - 2000
N2 - The definitions of the affinity tensor and the tensor of chemical potential of an immobile component of a solid are given. The mechanochemistry of a liquid is formulated. Mechanically anisotropic states of a solid and their influence on affinity are analyzed. Thermodynamic equations are deduced relating the chemical potential tensor to the stress and strain tensors. The mechanochemistry of an ideally elastic solid and of a solid with mobile components, as well as the mechanochemistry of an interface, are formulated. As an example, the mechanochemical effect of dissolution (evaporation) is considered including its dependence on the deformation sign.
AB - The definitions of the affinity tensor and the tensor of chemical potential of an immobile component of a solid are given. The mechanochemistry of a liquid is formulated. Mechanically anisotropic states of a solid and their influence on affinity are analyzed. Thermodynamic equations are deduced relating the chemical potential tensor to the stress and strain tensors. The mechanochemistry of an ideally elastic solid and of a solid with mobile components, as well as the mechanochemistry of an interface, are formulated. As an example, the mechanochemical effect of dissolution (evaporation) is considered including its dependence on the deformation sign.
UR - http://www.scopus.com/inward/record.url?scp=0034378221&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0034378221
VL - 70
SP - 329
EP - 356
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 3
ER -
ID: 95718371