Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Thermodynamic and magnetic properties of magnesium-gallium ferrite ceramics. / Kondrat'eva, O. N.; Nikiforova, G. E.; Tyurin, A. V.; Shevchenko, E. V.; Andrusenko, E. V.; Smirnova, M. N.; Ketsko, V. A.; Gavrichev, K. S.
в: Ceramics International, Том 44, № 4, 2017, стр. 4367-4374.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Thermodynamic and magnetic properties of magnesium-gallium ferrite ceramics
AU - Kondrat'eva, O. N.
AU - Nikiforova, G. E.
AU - Tyurin, A. V.
AU - Shevchenko, E. V.
AU - Andrusenko, E. V.
AU - Smirnova, M. N.
AU - Ketsko, V. A.
AU - Gavrichev, K. S.
PY - 2017
Y1 - 2017
N2 - A comparative study of the thermodynamic and magnetic properties of the Ga-substituted magnesium ferrite polycrystalline samples Mg(Fe1-x Ga x )2O4 with x = 0.2 and x = 0.4 was carried out. The low-temperature heat capacity of the sample with x = 0.2 was measured by adiabatic calorimetry. Based on the smoothed heat capacity data C p,m°(T) for Mg(Fe0.8Ga0.2)2O4, the standard thermodynamic functions were determined in a temperature range 2-800K. A broad heat capacity anomaly below 60K, which can be attributable to the magnetic order-disorder transition, was observed for both samples. The field-dependence of magnetizations in an applied magnetic field up to ± 50kOe revealed the ferrimagnetic behaviour of the samples. The values of Curie temperature (T C ) and the blocking temperature (T B ) were determined from ZFC-FC magnetization measurements. Based on the results of heat capacity and magnetic measurements, the low temperature state in the Mg(Fe0.6Ga0.4)2O4 sample may be attributed to a spin glass-like state.
AB - A comparative study of the thermodynamic and magnetic properties of the Ga-substituted magnesium ferrite polycrystalline samples Mg(Fe1-x Ga x )2O4 with x = 0.2 and x = 0.4 was carried out. The low-temperature heat capacity of the sample with x = 0.2 was measured by adiabatic calorimetry. Based on the smoothed heat capacity data C p,m°(T) for Mg(Fe0.8Ga0.2)2O4, the standard thermodynamic functions were determined in a temperature range 2-800K. A broad heat capacity anomaly below 60K, which can be attributable to the magnetic order-disorder transition, was observed for both samples. The field-dependence of magnetizations in an applied magnetic field up to ± 50kOe revealed the ferrimagnetic behaviour of the samples. The values of Curie temperature (T C ) and the blocking temperature (T B ) were determined from ZFC-FC magnetization measurements. Based on the results of heat capacity and magnetic measurements, the low temperature state in the Mg(Fe0.6Ga0.4)2O4 sample may be attributed to a spin glass-like state.
KW - Ferrites
KW - Heat capacity
KW - Magnetic properties
KW - Spinels
UR - http://www.scopus.com/inward/record.url?scp=85037583312&partnerID=8YFLogxK
U2 - 10.1016/j.ceramint.2017.12.031
DO - 10.1016/j.ceramint.2017.12.031
M3 - Article
AN - SCOPUS:85037583312
VL - 44
SP - 4367
EP - 4374
JO - Ceramics International
JF - Ceramics International
SN - 0272-8842
IS - 4
ER -
ID: 13344070