Результаты исследований: Научные публикации в периодических изданиях › статья
Theory and Practice of Alkyl Aromatic Hydrocarbon Synthesis. 1. Branched Alkylbenzenes. / Naumkin, P.V.; Nesterova, T.N.; Nesterov, I.A.; Toikka, A.M.; Shakun, V.A.
в: Industrial and Engineering Chemistry Research, Том 54, № 35, 2015, стр. 8629-8639.Результаты исследований: Научные публикации в периодических изданиях › статья
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TY - JOUR
T1 - Theory and Practice of Alkyl Aromatic Hydrocarbon Synthesis. 1. Branched Alkylbenzenes
AU - Naumkin, P.V.
AU - Nesterova, T.N.
AU - Nesterov, I.A.
AU - Toikka, A.M.
AU - Shakun, V.A.
PY - 2015
Y1 - 2015
N2 - The alkylation of benzene, toluene, ortho-xylene and biphenyl was carried out over aluminum halides and ion-exchange resin Amberlyst 36 Dry with use of branched C5 alkylating agents. Tertiary product selectivity is related to a catalytic system of aluminum halides with reduced activity or ion-exchange resin Amberlyst 36 Dry. High selectivity of branched secondary products is provided by an equilibrium condition. The equilibrium in a liquid phase of positional and structural isomerization, and transalkylation at 303 – 363 K was studied. The prediction method of an isomerization equilibrium was recommended for C5 branched alkylbenzenes.
AB - The alkylation of benzene, toluene, ortho-xylene and biphenyl was carried out over aluminum halides and ion-exchange resin Amberlyst 36 Dry with use of branched C5 alkylating agents. Tertiary product selectivity is related to a catalytic system of aluminum halides with reduced activity or ion-exchange resin Amberlyst 36 Dry. High selectivity of branched secondary products is provided by an equilibrium condition. The equilibrium in a liquid phase of positional and structural isomerization, and transalkylation at 303 – 363 K was studied. The prediction method of an isomerization equilibrium was recommended for C5 branched alkylbenzenes.
KW - Chemical equilibrium
KW - isomerization
KW - pentylbenzenes
U2 - 10.1021/acs.iecr.5b02021
DO - 10.1021/acs.iecr.5b02021
M3 - Article
VL - 54
SP - 8629
EP - 8639
JO - Industrial and Engineering Chemistry Process Design and Development
JF - Industrial and Engineering Chemistry Process Design and Development
SN - 0888-5885
IS - 35
ER -
ID: 3940967