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Theory and Practice of Alkyl Aromatic Hydrocarbon Synthesis. 1. Branched Alkylbenzenes. / Naumkin, P.V.; Nesterova, T.N.; Nesterov, I.A.; Toikka, A.M.; Shakun, V.A.

In: Industrial and Engineering Chemistry Research, Vol. 54, No. 35, 2015, p. 8629-8639.

Research output: Contribution to journal › Article

Harvard

Naumkin, PV, Nesterova, TN, Nesterov, IA, Toikka, AM & Shakun, VA 2015, 'Theory and Practice of Alkyl Aromatic Hydrocarbon Synthesis. 1. Branched Alkylbenzenes', Industrial and Engineering Chemistry Research, vol. 54, no. 35, pp. 8629-8639. https://doi.org/10.1021/acs.iecr.5b02021

APA

Naumkin, P. V., Nesterova, T. N., Nesterov, I. A., Toikka, A. M., & Shakun, V. A. (2015). Theory and Practice of Alkyl Aromatic Hydrocarbon Synthesis. 1. Branched Alkylbenzenes. Industrial and Engineering Chemistry Research, 54(35), 8629-8639. https://doi.org/10.1021/acs.iecr.5b02021

Vancouver

Naumkin PV, Nesterova TN, Nesterov IA, Toikka AM, Shakun VA. Theory and Practice of Alkyl Aromatic Hydrocarbon Synthesis. 1. Branched Alkylbenzenes. Industrial and Engineering Chemistry Research. 2015;54(35):8629-8639. https://doi.org/10.1021/acs.iecr.5b02021

Author

Naumkin, P.V. ; Nesterova, T.N. ; Nesterov, I.A. ; Toikka, A.M. ; Shakun, V.A. / Theory and Practice of Alkyl Aromatic Hydrocarbon Synthesis. 1. Branched Alkylbenzenes. In: Industrial and Engineering Chemistry Research. 2015 ; Vol. 54, No. 35. pp. 8629-8639.

BibTeX

@article{1433c40e2de94e33aa918cbf41757a92,
title = "Theory and Practice of Alkyl Aromatic Hydrocarbon Synthesis. 1. Branched Alkylbenzenes",
abstract = "The alkylation of benzene, toluene, ortho-xylene and biphenyl was carried out over aluminum halides and ion-exchange resin Amberlyst 36 Dry with use of branched C5 alkylating agents. Tertiary product selectivity is related to a catalytic system of aluminum halides with reduced activity or ion-exchange resin Amberlyst 36 Dry. High selectivity of branched secondary products is provided by an equilibrium condition. The equilibrium in a liquid phase of positional and structural isomerization, and transalkylation at 303 – 363 K was studied. The prediction method of an isomerization equilibrium was recommended for C5 branched alkylbenzenes.",
keywords = "Chemical equilibrium, isomerization, pentylbenzenes",
author = "P.V. Naumkin and T.N. Nesterova and I.A. Nesterov and A.M. Toikka and V.A. Shakun",
year = "2015",
doi = "10.1021/acs.iecr.5b02021",
language = "English",
volume = "54",
pages = "8629--8639",
journal = "Industrial and Engineering Chemistry Process Design and Development",
issn = "0888-5885",
publisher = "American Chemical Society",
number = "35",

}

RIS

TY - JOUR

T1 - Theory and Practice of Alkyl Aromatic Hydrocarbon Synthesis. 1. Branched Alkylbenzenes

AU - Naumkin, P.V.

AU - Nesterova, T.N.

AU - Nesterov, I.A.

AU - Toikka, A.M.

AU - Shakun, V.A.

PY - 2015

Y1 - 2015

N2 - The alkylation of benzene, toluene, ortho-xylene and biphenyl was carried out over aluminum halides and ion-exchange resin Amberlyst 36 Dry with use of branched C5 alkylating agents. Tertiary product selectivity is related to a catalytic system of aluminum halides with reduced activity or ion-exchange resin Amberlyst 36 Dry. High selectivity of branched secondary products is provided by an equilibrium condition. The equilibrium in a liquid phase of positional and structural isomerization, and transalkylation at 303 – 363 K was studied. The prediction method of an isomerization equilibrium was recommended for C5 branched alkylbenzenes.

AB - The alkylation of benzene, toluene, ortho-xylene and biphenyl was carried out over aluminum halides and ion-exchange resin Amberlyst 36 Dry with use of branched C5 alkylating agents. Tertiary product selectivity is related to a catalytic system of aluminum halides with reduced activity or ion-exchange resin Amberlyst 36 Dry. High selectivity of branched secondary products is provided by an equilibrium condition. The equilibrium in a liquid phase of positional and structural isomerization, and transalkylation at 303 – 363 K was studied. The prediction method of an isomerization equilibrium was recommended for C5 branched alkylbenzenes.

KW - Chemical equilibrium

KW - isomerization

KW - pentylbenzenes

U2 - 10.1021/acs.iecr.5b02021

DO - 10.1021/acs.iecr.5b02021

M3 - Article

VL - 54

SP - 8629

EP - 8639

JO - Industrial and Engineering Chemistry Process Design and Development

JF - Industrial and Engineering Chemistry Process Design and Development

SN - 0888-5885

IS - 35

ER -

ID: 3940967