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The study of bis-chloromethyl-phosphinic acid crystal by ATR and Raman spectroscopy and X-ray diffraction. / Glazachev, Eugeny V.; Avdontceva, Margarita S.; Asfin, Ruslan E.
в: Molecular Crystals and Liquid Crystals, Том 665, № 1, 13.04.2018, стр. 219-227.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - The study of bis-chloromethyl-phosphinic acid crystal by ATR and Raman spectroscopy and X-ray diffraction
AU - Glazachev, Eugeny V.
AU - Avdontceva, Margarita S.
AU - Asfin, Ruslan E.
PY - 2018/4/13
Y1 - 2018/4/13
N2 - Crystals of bis-chloromethyl-phosphinic acid ((CH 2 Cl) 2 POOH) are studied by attenuated total reflection (ATR) and Raman spectroscopy supported by X-Ray diffraction. The bands recorded in the ATR and in Raman spectra have the same wavenumbers within experimental uncertainty. It is in agreement with the X-Ray diffraction results which show that the molecules in crystals form infinite chains through hydrogen bonds and there is no center of inversion. The parameters of the unit cell, the bond lengths and angles, and the distance between two oxygen atoms in hydrogen bond bridges are determined. The spectral features and the intermolecular distance between oxygen atoms are characteristic for a strong hydrogen bonded system.
AB - Crystals of bis-chloromethyl-phosphinic acid ((CH 2 Cl) 2 POOH) are studied by attenuated total reflection (ATR) and Raman spectroscopy supported by X-Ray diffraction. The bands recorded in the ATR and in Raman spectra have the same wavenumbers within experimental uncertainty. It is in agreement with the X-Ray diffraction results which show that the molecules in crystals form infinite chains through hydrogen bonds and there is no center of inversion. The parameters of the unit cell, the bond lengths and angles, and the distance between two oxygen atoms in hydrogen bond bridges are determined. The spectral features and the intermolecular distance between oxygen atoms are characteristic for a strong hydrogen bonded system.
KW - (CH Cl) POOH
KW - ATR spectra
KW - crystal structure
KW - H-bond
KW - Raman spectra
KW - X-Ray diffraction
UR - http://www.scopus.com/inward/record.url?scp=85061664935&partnerID=8YFLogxK
U2 - 10.1080/15421406.2018.1513389
DO - 10.1080/15421406.2018.1513389
M3 - Article
AN - SCOPUS:85061664935
VL - 665
SP - 219
EP - 227
JO - Molecular Crystals and Liquid Crystals
JF - Molecular Crystals and Liquid Crystals
SN - 1542-1406
IS - 1
ER -
ID: 39089513