Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The RgI2 (ion-pair states) van der Waals complexes. / Baturo, Vera V.; Lukashov, Sergey S.; Poretsky, Sergey A.; Pravilov, Anatoly M.
в: European Physical Journal D, Том 71, № 9, 2017, стр. 227.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - The RgI2 (ion-pair states) van der Waals complexes
AU - Baturo, Vera V.
AU - Lukashov, Sergey S.
AU - Poretsky, Sergey A.
AU - Pravilov, Anatoly M.
PY - 2017
Y1 - 2017
N2 - This paper is an overview of our recent experimental investigations of the RgI2 van der Waals complexes, Rg = He, Ar, Kr, performed by means of laser induced fluorescence spectroscopy, optical-optical double resonance and supersonic molecular beam techniques. Spectroscopic parameters of these complexes in the E0 g+ ion-pair state, such as binding energies and several spectroscopic constants, have been determined. Most likely, the potential energy surfaces of the all RgI2(E) complexes under study present T-shaped minima. Vibrational and electronic predissociations of the RgI2(E) complexes were analyzed. Relative contributions of the different electronic predissociation channels and vibrational distributions of the decay products were determined. Possible mechanisms of the complexes decay are suggested and discussed.
AB - This paper is an overview of our recent experimental investigations of the RgI2 van der Waals complexes, Rg = He, Ar, Kr, performed by means of laser induced fluorescence spectroscopy, optical-optical double resonance and supersonic molecular beam techniques. Spectroscopic parameters of these complexes in the E0 g+ ion-pair state, such as binding energies and several spectroscopic constants, have been determined. Most likely, the potential energy surfaces of the all RgI2(E) complexes under study present T-shaped minima. Vibrational and electronic predissociations of the RgI2(E) complexes were analyzed. Relative contributions of the different electronic predissociation channels and vibrational distributions of the decay products were determined. Possible mechanisms of the complexes decay are suggested and discussed.
U2 - 10.1140/epjd/e2017-80142-6
DO - 10.1140/epjd/e2017-80142-6
M3 - статья
VL - 71
SP - 227
JO - European Physical Journal D
JF - European Physical Journal D
SN - 1434-6060
IS - 9
ER -
ID: 9160523