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The RgI2 (ion-pair states) van der Waals complexes. / Baturo, Vera V.; Lukashov, Sergey S.; Poretsky, Sergey A.; Pravilov, Anatoly M.

In: European Physical Journal D, Vol. 71, No. 9, 2017, p. 227.

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@article{d05757ec291b4baa9353a6a1d4968a2a,
title = "The RgI2 (ion-pair states) van der Waals complexes",
abstract = "This paper is an overview of our recent experimental investigations of the RgI2 van der Waals complexes, Rg = He, Ar, Kr, performed by means of laser induced fluorescence spectroscopy, optical-optical double resonance and supersonic molecular beam techniques. Spectroscopic parameters of these complexes in the E0 g+ ion-pair state, such as binding energies and several spectroscopic constants, have been determined. Most likely, the potential energy surfaces of the all RgI2(E) complexes under study present T-shaped minima. Vibrational and electronic predissociations of the RgI2(E) complexes were analyzed. Relative contributions of the different electronic predissociation channels and vibrational distributions of the decay products were determined. Possible mechanisms of the complexes decay are suggested and discussed.",
author = "Baturo, {Vera V.} and Lukashov, {Sergey S.} and Poretsky, {Sergey A.} and Pravilov, {Anatoly M.}",
year = "2017",
doi = "10.1140/epjd/e2017-80142-6",
language = "русский",
volume = "71",
pages = "227",
journal = "European Physical Journal D",
issn = "1434-6060",
publisher = "Springer Nature",
number = "9",

}

RIS

TY - JOUR

T1 - The RgI2 (ion-pair states) van der Waals complexes

AU - Baturo, Vera V.

AU - Lukashov, Sergey S.

AU - Poretsky, Sergey A.

AU - Pravilov, Anatoly M.

PY - 2017

Y1 - 2017

N2 - This paper is an overview of our recent experimental investigations of the RgI2 van der Waals complexes, Rg = He, Ar, Kr, performed by means of laser induced fluorescence spectroscopy, optical-optical double resonance and supersonic molecular beam techniques. Spectroscopic parameters of these complexes in the E0 g+ ion-pair state, such as binding energies and several spectroscopic constants, have been determined. Most likely, the potential energy surfaces of the all RgI2(E) complexes under study present T-shaped minima. Vibrational and electronic predissociations of the RgI2(E) complexes were analyzed. Relative contributions of the different electronic predissociation channels and vibrational distributions of the decay products were determined. Possible mechanisms of the complexes decay are suggested and discussed.

AB - This paper is an overview of our recent experimental investigations of the RgI2 van der Waals complexes, Rg = He, Ar, Kr, performed by means of laser induced fluorescence spectroscopy, optical-optical double resonance and supersonic molecular beam techniques. Spectroscopic parameters of these complexes in the E0 g+ ion-pair state, such as binding energies and several spectroscopic constants, have been determined. Most likely, the potential energy surfaces of the all RgI2(E) complexes under study present T-shaped minima. Vibrational and electronic predissociations of the RgI2(E) complexes were analyzed. Relative contributions of the different electronic predissociation channels and vibrational distributions of the decay products were determined. Possible mechanisms of the complexes decay are suggested and discussed.

U2 - 10.1140/epjd/e2017-80142-6

DO - 10.1140/epjd/e2017-80142-6

M3 - статья

VL - 71

SP - 227

JO - European Physical Journal D

JF - European Physical Journal D

SN - 1434-6060

IS - 9

ER -

ID: 9160523