DOI

Theories of micellization based on the application of the mass action law to aggregation processes in surfactant solutions are reviewed. The rigorous thermodynamic justification of the approach, explanation of the critical micelle concentration, inter-relations between the main micellization parameters, and an analysis of the surface tension isotherm of a micellar solution are given. Properties of ionic micellar systems, including counterion binding and the behavior of free monomeric ions, are discussed in detail with illustrative estimations for sodium dodecylsulfate and other surfactants.

Язык оригиналаанглийский
Страницы (с-по)1-78
Число страниц78
ЖурналAdvances in Colloid and Interface Science
Том45
Номер выпускаC
DOI
СостояниеОпубликовано - 30 сен 1993

    Предметные области Scopus

  • Поверхности и интерфейсы
  • Физическая и теоретическая химия
  • Коллоидная химия и химия поверхности

ID: 95722750