Theories of micellization based on the application of the mass action law to aggregation processes in surfactant solutions are reviewed. The rigorous thermodynamic justification of the approach, explanation of the critical micelle concentration, inter-relations between the main micellization parameters, and an analysis of the surface tension isotherm of a micellar solution are given. Properties of ionic micellar systems, including counterion binding and the behavior of free monomeric ions, are discussed in detail with illustrative estimations for sodium dodecylsulfate and other surfactants.

Original languageEnglish
Pages (from-to)1-78
Number of pages78
JournalAdvances in Colloid and Interface Science
Volume45
Issue numberC
DOIs
StatePublished - 30 Sep 1993

    Scopus subject areas

  • Surfaces and Interfaces
  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

ID: 95722750