Standard

Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters. / Miroslavov, A.E.; Polotskii, Y.S.; Gurzhiy, V.V.; Ivanov, A.Y.; Lumpov, A.A.; Tyupina, M.Y.; Sidorenko, G.V.; Tolstoy, P.M.; Maltsev, D.A.; Suglobov, D.N.

в: Inorganic Chemistry, Том 53, № 15, 2014, стр. 7861-7869.

Результаты исследований: Научные публикации в периодических изданиях › статья

Harvard

Miroslavov, AE, Polotskii, YS, Gurzhiy, VV, Ivanov, AY, Lumpov, AA, Tyupina, MY, Sidorenko, GV, Tolstoy, PM, Maltsev, DA & Suglobov, DN 2014, 'Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters', Inorganic Chemistry, Том. 53, № 15, стр. 7861-7869. https://doi.org/10.1021/ic500327s

APA

Miroslavov, A. E., Polotskii, Y. S., Gurzhiy, V. V., Ivanov, A. Y., Lumpov, A. A., Tyupina, M. Y., Sidorenko, G. V., Tolstoy, P. M., Maltsev, D. A., & Suglobov, D. N. (2014). Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters. Inorganic Chemistry, 53(15), 7861-7869. https://doi.org/10.1021/ic500327s

Vancouver

Miroslavov AE, Polotskii YS, Gurzhiy VV, Ivanov AY, Lumpov AA, Tyupina MY и пр. Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters. Inorganic Chemistry. 2014;53(15):7861-7869. https://doi.org/10.1021/ic500327s

Author

Miroslavov, A.E. ; Polotskii, Y.S. ; Gurzhiy, V.V. ; Ivanov, A.Y. ; Lumpov, A.A. ; Tyupina, M.Y. ; Sidorenko, G.V. ; Tolstoy, P.M. ; Maltsev, D.A. ; Suglobov, D.N. / Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters. в: Inorganic Chemistry. 2014 ; Том 53, № 15. стр. 7861-7869.

BibTeX

@article{b717f87f58bd48858e97356c77fd5e3f,
title = "Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters",
abstract = "Technetium(I) and rhenium(I) pentacarbonyl complexes with ethyl 2-isocyanoacetate and methyl 11-isocyanoundecanoate, [M(CO)(5)(CNCH2COOEt)]ClO4 (M = Tc (1) and Re (2)) and [M(CO)(5)(CN(CH2)(10)COOMe)]ClO4 (M = Tc (3) and Re (4)), were prepared and characterized by IR, H-1 NMR, and C-13{H-1} NMR spectroscopy. The crystal structures of 1 and 2 were determined using single-crystal X-ray diffraction. The kinetics of thermal decarbonylation of technetium complexes 1 and 3 in ethylene glycol was studied by IR spectroscopy. The rate constants and activation parameters of this reaction were determined and compared with those for [Tc(CO)(6)](+). It was found that rhenium complexes 2 and 4 were stable with respect to thermal decarbonylation. Histidine challenge reaction of complexes 1 and 2 in phosphate buffer was examined by IR spectroscopy. In the presence of histidine, the rhenium pentacarbonyl isocyanide complex partially decomposes to form an unidentified yellow precipitate. Technetium analogue 1 is more stable un",
author = "A.E. Miroslavov and Y.S. Polotskii and V.V. Gurzhiy and A.Y. Ivanov and A.A. Lumpov and M.Y. Tyupina and G.V. Sidorenko and P.M. Tolstoy and D.A. Maltsev and D.N. Suglobov",
year = "2014",
doi = "10.1021/ic500327s",
language = "English",
volume = "53",
pages = "7861--7869",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "15",

}

RIS

TY - JOUR

T1 - Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters

AU - Miroslavov, A.E.

AU - Polotskii, Y.S.

AU - Gurzhiy, V.V.

AU - Ivanov, A.Y.

AU - Lumpov, A.A.

AU - Tyupina, M.Y.

AU - Sidorenko, G.V.

AU - Tolstoy, P.M.

AU - Maltsev, D.A.

AU - Suglobov, D.N.

PY - 2014

Y1 - 2014

N2 - Technetium(I) and rhenium(I) pentacarbonyl complexes with ethyl 2-isocyanoacetate and methyl 11-isocyanoundecanoate, [M(CO)(5)(CNCH2COOEt)]ClO4 (M = Tc (1) and Re (2)) and [M(CO)(5)(CN(CH2)(10)COOMe)]ClO4 (M = Tc (3) and Re (4)), were prepared and characterized by IR, H-1 NMR, and C-13{H-1} NMR spectroscopy. The crystal structures of 1 and 2 were determined using single-crystal X-ray diffraction. The kinetics of thermal decarbonylation of technetium complexes 1 and 3 in ethylene glycol was studied by IR spectroscopy. The rate constants and activation parameters of this reaction were determined and compared with those for [Tc(CO)(6)](+). It was found that rhenium complexes 2 and 4 were stable with respect to thermal decarbonylation. Histidine challenge reaction of complexes 1 and 2 in phosphate buffer was examined by IR spectroscopy. In the presence of histidine, the rhenium pentacarbonyl isocyanide complex partially decomposes to form an unidentified yellow precipitate. Technetium analogue 1 is more stable un

AB - Technetium(I) and rhenium(I) pentacarbonyl complexes with ethyl 2-isocyanoacetate and methyl 11-isocyanoundecanoate, [M(CO)(5)(CNCH2COOEt)]ClO4 (M = Tc (1) and Re (2)) and [M(CO)(5)(CN(CH2)(10)COOMe)]ClO4 (M = Tc (3) and Re (4)), were prepared and characterized by IR, H-1 NMR, and C-13{H-1} NMR spectroscopy. The crystal structures of 1 and 2 were determined using single-crystal X-ray diffraction. The kinetics of thermal decarbonylation of technetium complexes 1 and 3 in ethylene glycol was studied by IR spectroscopy. The rate constants and activation parameters of this reaction were determined and compared with those for [Tc(CO)(6)](+). It was found that rhenium complexes 2 and 4 were stable with respect to thermal decarbonylation. Histidine challenge reaction of complexes 1 and 2 in phosphate buffer was examined by IR spectroscopy. In the presence of histidine, the rhenium pentacarbonyl isocyanide complex partially decomposes to form an unidentified yellow precipitate. Technetium analogue 1 is more stable un

U2 - 10.1021/ic500327s

DO - 10.1021/ic500327s

M3 - Article

VL - 53

SP - 7861

EP - 7869

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 15

ER -

ID: 7011887