Standard

Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters. / Miroslavov, A.E.; Polotskii, Y.S.; Gurzhiy, V.V.; Ivanov, A.Y.; Lumpov, A.A.; Tyupina, M.Y.; Sidorenko, G.V.; Tolstoy, P.M.; Maltsev, D.A.; Suglobov, D.N.

In: Inorganic Chemistry, Vol. 53, No. 15, 2014, p. 7861-7869.

Research output: Contribution to journal › Article

Harvard

Miroslavov, AE, Polotskii, YS, Gurzhiy, VV, Ivanov, AY, Lumpov, AA, Tyupina, MY, Sidorenko, GV, Tolstoy, PM, Maltsev, DA & Suglobov, DN 2014, 'Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters', Inorganic Chemistry, vol. 53, no. 15, pp. 7861-7869. https://doi.org/10.1021/ic500327s

APA

Miroslavov, A. E., Polotskii, Y. S., Gurzhiy, V. V., Ivanov, A. Y., Lumpov, A. A., Tyupina, M. Y., Sidorenko, G. V., Tolstoy, P. M., Maltsev, D. A., & Suglobov, D. N. (2014). Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters. Inorganic Chemistry, 53(15), 7861-7869. https://doi.org/10.1021/ic500327s

Vancouver

Miroslavov AE, Polotskii YS, Gurzhiy VV, Ivanov AY, Lumpov AA, Tyupina MY et al. Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters. Inorganic Chemistry. 2014;53(15):7861-7869. https://doi.org/10.1021/ic500327s

Author

Miroslavov, A.E. ; Polotskii, Y.S. ; Gurzhiy, V.V. ; Ivanov, A.Y. ; Lumpov, A.A. ; Tyupina, M.Y. ; Sidorenko, G.V. ; Tolstoy, P.M. ; Maltsev, D.A. ; Suglobov, D.N. / Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters. In: Inorganic Chemistry. 2014 ; Vol. 53, No. 15. pp. 7861-7869.

BibTeX

@article{b717f87f58bd48858e97356c77fd5e3f,
title = "Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters",
abstract = "Technetium(I) and rhenium(I) pentacarbonyl complexes with ethyl 2-isocyanoacetate and methyl 11-isocyanoundecanoate, [M(CO)(5)(CNCH2COOEt)]ClO4 (M = Tc (1) and Re (2)) and [M(CO)(5)(CN(CH2)(10)COOMe)]ClO4 (M = Tc (3) and Re (4)), were prepared and characterized by IR, H-1 NMR, and C-13{H-1} NMR spectroscopy. The crystal structures of 1 and 2 were determined using single-crystal X-ray diffraction. The kinetics of thermal decarbonylation of technetium complexes 1 and 3 in ethylene glycol was studied by IR spectroscopy. The rate constants and activation parameters of this reaction were determined and compared with those for [Tc(CO)(6)](+). It was found that rhenium complexes 2 and 4 were stable with respect to thermal decarbonylation. Histidine challenge reaction of complexes 1 and 2 in phosphate buffer was examined by IR spectroscopy. In the presence of histidine, the rhenium pentacarbonyl isocyanide complex partially decomposes to form an unidentified yellow precipitate. Technetium analogue 1 is more stable un",
author = "A.E. Miroslavov and Y.S. Polotskii and V.V. Gurzhiy and A.Y. Ivanov and A.A. Lumpov and M.Y. Tyupina and G.V. Sidorenko and P.M. Tolstoy and D.A. Maltsev and D.N. Suglobov",
year = "2014",
doi = "10.1021/ic500327s",
language = "English",
volume = "53",
pages = "7861--7869",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "15",

}

RIS

TY - JOUR

T1 - Technetium and Rhenium Pentacarbonyl Complexes with C2 and C11 ω‑Isocyanocarboxylic Acid Esters

AU - Miroslavov, A.E.

AU - Polotskii, Y.S.

AU - Gurzhiy, V.V.

AU - Ivanov, A.Y.

AU - Lumpov, A.A.

AU - Tyupina, M.Y.

AU - Sidorenko, G.V.

AU - Tolstoy, P.M.

AU - Maltsev, D.A.

AU - Suglobov, D.N.

PY - 2014

Y1 - 2014

N2 - Technetium(I) and rhenium(I) pentacarbonyl complexes with ethyl 2-isocyanoacetate and methyl 11-isocyanoundecanoate, [M(CO)(5)(CNCH2COOEt)]ClO4 (M = Tc (1) and Re (2)) and [M(CO)(5)(CN(CH2)(10)COOMe)]ClO4 (M = Tc (3) and Re (4)), were prepared and characterized by IR, H-1 NMR, and C-13{H-1} NMR spectroscopy. The crystal structures of 1 and 2 were determined using single-crystal X-ray diffraction. The kinetics of thermal decarbonylation of technetium complexes 1 and 3 in ethylene glycol was studied by IR spectroscopy. The rate constants and activation parameters of this reaction were determined and compared with those for [Tc(CO)(6)](+). It was found that rhenium complexes 2 and 4 were stable with respect to thermal decarbonylation. Histidine challenge reaction of complexes 1 and 2 in phosphate buffer was examined by IR spectroscopy. In the presence of histidine, the rhenium pentacarbonyl isocyanide complex partially decomposes to form an unidentified yellow precipitate. Technetium analogue 1 is more stable un

AB - Technetium(I) and rhenium(I) pentacarbonyl complexes with ethyl 2-isocyanoacetate and methyl 11-isocyanoundecanoate, [M(CO)(5)(CNCH2COOEt)]ClO4 (M = Tc (1) and Re (2)) and [M(CO)(5)(CN(CH2)(10)COOMe)]ClO4 (M = Tc (3) and Re (4)), were prepared and characterized by IR, H-1 NMR, and C-13{H-1} NMR spectroscopy. The crystal structures of 1 and 2 were determined using single-crystal X-ray diffraction. The kinetics of thermal decarbonylation of technetium complexes 1 and 3 in ethylene glycol was studied by IR spectroscopy. The rate constants and activation parameters of this reaction were determined and compared with those for [Tc(CO)(6)](+). It was found that rhenium complexes 2 and 4 were stable with respect to thermal decarbonylation. Histidine challenge reaction of complexes 1 and 2 in phosphate buffer was examined by IR spectroscopy. In the presence of histidine, the rhenium pentacarbonyl isocyanide complex partially decomposes to form an unidentified yellow precipitate. Technetium analogue 1 is more stable un

U2 - 10.1021/ic500327s

DO - 10.1021/ic500327s

M3 - Article

VL - 53

SP - 7861

EP - 7869

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 15

ER -

ID: 7011887