Standard

Structural transformations and phase transition froodite (α–PdBi2) — urvantsevite (β–PdBi2) at high temperature. / Karimova, Oxana V.; Eremin, N. N.; Mezhueva, A. A.; Uporova, N. S.; Zolotarev, A. A.; Chareev, D. A.

в: ВЕСТНИК МОСКОВСКОГО УНИВЕРСИТЕТА. СЕРИЯ 4: ГЕОЛОГИЯ, Том 64, № 1, 01.01.2025, стр. 3-9.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Karimova, OV, Eremin, NN, Mezhueva, AA, Uporova, NS, Zolotarev, AA & Chareev, DA 2025, 'Structural transformations and phase transition froodite (α–PdBi2) — urvantsevite (β–PdBi2) at high temperature', ВЕСТНИК МОСКОВСКОГО УНИВЕРСИТЕТА. СЕРИЯ 4: ГЕОЛОГИЯ, Том. 64, № 1, стр. 3-9. https://doi.org/10.55959/msu0579-9406-4-2025-64-1-3-9

APA

Karimova, O. V., Eremin, N. N., Mezhueva, A. A., Uporova, N. S., Zolotarev, A. A., & Chareev, D. A. (2025). Structural transformations and phase transition froodite (α–PdBi2) — urvantsevite (β–PdBi2) at high temperature. ВЕСТНИК МОСКОВСКОГО УНИВЕРСИТЕТА. СЕРИЯ 4: ГЕОЛОГИЯ, 64(1), 3-9. https://doi.org/10.55959/msu0579-9406-4-2025-64-1-3-9

Vancouver

Karimova OV, Eremin NN, Mezhueva AA, Uporova NS, Zolotarev AA, Chareev DA. Structural transformations and phase transition froodite (α–PdBi2) — urvantsevite (β–PdBi2) at high temperature. ВЕСТНИК МОСКОВСКОГО УНИВЕРСИТЕТА. СЕРИЯ 4: ГЕОЛОГИЯ. 2025 Янв. 1;64(1):3-9. https://doi.org/10.55959/msu0579-9406-4-2025-64-1-3-9

Author

Karimova, Oxana V. ; Eremin, N. N. ; Mezhueva, A. A. ; Uporova, N. S. ; Zolotarev, A. A. ; Chareev, D. A. / Structural transformations and phase transition froodite (α–PdBi2) — urvantsevite (β–PdBi2) at high temperature. в: ВЕСТНИК МОСКОВСКОГО УНИВЕРСИТЕТА. СЕРИЯ 4: ГЕОЛОГИЯ. 2025 ; Том 64, № 1. стр. 3-9.

BibTeX

@article{5c8c753451374550a8069fd7694b2af2,
title = "Structural transformations and phase transition froodite (α–PdBi2) — urvantsevite (β–PdBi2) at high temperature",
abstract = "The phase transition in the structure of the PdBi2 compound was studied using high-temperature in-situ methods (differential thermal analysis, high-temperature single-crystal X-ray diffraction). The structures of PdBi2 polymorphic modifications were refined at temperatures of 300, 373, 473, 573 and 637 K based on the high-temperature single-crystal X-ray diffraction data. A low-temperature modification of α-PdBi2 is monoclinic, space group C2/m (a = 12.726(1)A, b = 4.2605(4)A, c = 5.5668(5)A, β = 102.51(1) °, V = 299.95(5)A3, Z = 2). It is stable in the temperature range from 300K (27 °C) to 573K (300 °С) and is corresponding to the mineral froodite. A high-temperature modification of β-PdBi2 was fixed at the temperature 673K (400 °C). The phase β-PdBi2 is structural analogue of the mineral urvancevite: it{\textquoteright}s tetragonal, space group I4/mmm (a = 3.3876(3) A, c = 13.092(2) A, V = 150.24(4) A3, Z = 1). The phase transition refers to a type I and is a reconstructive polymorphic transformation with a rearrangement of the first coordination sphere.",
author = "Karimova, {Oxana V.} and Eremin, {N. N.} and Mezhueva, {A. A.} and Uporova, {N. S.} and Zolotarev, {A. A.} and Chareev, {D. A.}",
year = "2025",
month = jan,
day = "1",
doi = "10.55959/msu0579-9406-4-2025-64-1-3-9",
language = "English",
volume = "64",
pages = "3--9",
journal = "Vestnik Moskovskogo Universiteta, Seriya 4: Geologiya",
issn = "0579-9406",
publisher = "Издательство Московского университета",
number = "1",

}

RIS

TY - JOUR

T1 - Structural transformations and phase transition froodite (α–PdBi2) — urvantsevite (β–PdBi2) at high temperature

AU - Karimova, Oxana V.

AU - Eremin, N. N.

AU - Mezhueva, A. A.

AU - Uporova, N. S.

AU - Zolotarev, A. A.

AU - Chareev, D. A.

PY - 2025/1/1

Y1 - 2025/1/1

N2 - The phase transition in the structure of the PdBi2 compound was studied using high-temperature in-situ methods (differential thermal analysis, high-temperature single-crystal X-ray diffraction). The structures of PdBi2 polymorphic modifications were refined at temperatures of 300, 373, 473, 573 and 637 K based on the high-temperature single-crystal X-ray diffraction data. A low-temperature modification of α-PdBi2 is monoclinic, space group C2/m (a = 12.726(1)A, b = 4.2605(4)A, c = 5.5668(5)A, β = 102.51(1) °, V = 299.95(5)A3, Z = 2). It is stable in the temperature range from 300K (27 °C) to 573K (300 °С) and is corresponding to the mineral froodite. A high-temperature modification of β-PdBi2 was fixed at the temperature 673K (400 °C). The phase β-PdBi2 is structural analogue of the mineral urvancevite: it’s tetragonal, space group I4/mmm (a = 3.3876(3) A, c = 13.092(2) A, V = 150.24(4) A3, Z = 1). The phase transition refers to a type I and is a reconstructive polymorphic transformation with a rearrangement of the first coordination sphere.

AB - The phase transition in the structure of the PdBi2 compound was studied using high-temperature in-situ methods (differential thermal analysis, high-temperature single-crystal X-ray diffraction). The structures of PdBi2 polymorphic modifications were refined at temperatures of 300, 373, 473, 573 and 637 K based on the high-temperature single-crystal X-ray diffraction data. A low-temperature modification of α-PdBi2 is monoclinic, space group C2/m (a = 12.726(1)A, b = 4.2605(4)A, c = 5.5668(5)A, β = 102.51(1) °, V = 299.95(5)A3, Z = 2). It is stable in the temperature range from 300K (27 °C) to 573K (300 °С) and is corresponding to the mineral froodite. A high-temperature modification of β-PdBi2 was fixed at the temperature 673K (400 °C). The phase β-PdBi2 is structural analogue of the mineral urvancevite: it’s tetragonal, space group I4/mmm (a = 3.3876(3) A, c = 13.092(2) A, V = 150.24(4) A3, Z = 1). The phase transition refers to a type I and is a reconstructive polymorphic transformation with a rearrangement of the first coordination sphere.

UR - https://www.mendeley.com/catalogue/0e20eb3e-77f7-3181-9cfe-76744b4b93e9/

U2 - 10.55959/msu0579-9406-4-2025-64-1-3-9

DO - 10.55959/msu0579-9406-4-2025-64-1-3-9

M3 - Article

VL - 64

SP - 3

EP - 9

JO - Vestnik Moskovskogo Universiteta, Seriya 4: Geologiya

JF - Vestnik Moskovskogo Universiteta, Seriya 4: Geologiya

SN - 0579-9406

IS - 1

ER -

ID: 135531548