Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Self-assembly of protonated 1,12-dodecanediamine molecules and strongly undulated uranyl selenate sheets in the structure of amine-templated uranyl selenate:(H3O)2[C12H30N 2]3[(UO2)4(SeO4) 8](H2O)5. / Krivovichev, Sergey V.; Kahlenberg, Volker; Avdontseva, Evgeniya Yu; Mersdorf, Edgar; Kaindl, Reinhard.
в: European Journal of Inorganic Chemistry, № 9, 06.05.2005, стр. 1653-1656.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Self-assembly of protonated 1,12-dodecanediamine molecules and strongly undulated uranyl selenate sheets in the structure of amine-templated uranyl selenate:(H3O)2[C12H30N 2]3[(UO2)4(SeO4) 8](H2O)5
AU - Krivovichev, Sergey V.
AU - Kahlenberg, Volker
AU - Avdontseva, Evgeniya Yu
AU - Mersdorf, Edgar
AU - Kaindl, Reinhard
PY - 2005/5/6
Y1 - 2005/5/6
N2 - The amine-templated uranyl selenate (H3O)2[C 12H30N2]3-[(UO2) 4(SeO4)8](H2O)5 (1) has been prepared. Its structure [monoclinic, P21/n, a = 11.3437(7), b = 24.8042(12), c = 29.2496(19) Å, β= 96.701(5)°, V = 8173.8(8) Å3, Z = 4, R1 = 0.083] is based upon strongly undulating [(UO2)(SeO4)2]2- sheets consisting of corner-sharing UO7 bipyramids and SeO4 2- tetrahedra. The undulations of the adjacent sheets have an anti-phase character that allows the formation of large eliptical channels that are occupied by rod micelles formed by self-assembly of protonated 1,12-dodecanediamine molecules.
AB - The amine-templated uranyl selenate (H3O)2[C 12H30N2]3-[(UO2) 4(SeO4)8](H2O)5 (1) has been prepared. Its structure [monoclinic, P21/n, a = 11.3437(7), b = 24.8042(12), c = 29.2496(19) Å, β= 96.701(5)°, V = 8173.8(8) Å3, Z = 4, R1 = 0.083] is based upon strongly undulating [(UO2)(SeO4)2]2- sheets consisting of corner-sharing UO7 bipyramids and SeO4 2- tetrahedra. The undulations of the adjacent sheets have an anti-phase character that allows the formation of large eliptical channels that are occupied by rod micelles formed by self-assembly of protonated 1,12-dodecanediamine molecules.
KW - Host-guest systems
KW - Layered compounds
KW - Selenium
KW - Self-assembly
KW - Uranium
UR - http://www.scopus.com/inward/record.url?scp=18844388983&partnerID=8YFLogxK
U2 - 10.1002/ejic.200500057
DO - 10.1002/ejic.200500057
M3 - Article
AN - SCOPUS:18844388983
SP - 1653
EP - 1656
JO - Berichte der deutschen chemischen Gesellschaft
JF - Berichte der deutschen chemischen Gesellschaft
SN - 0365-9496
IS - 9
ER -
ID: 49256819